Although desalination technologies have been widely adopted as a means to produce freshwater, many of them require large installations and access to advanced infrastructure. Recently, floating structures for solar evaporation have been proposed, employing the concept of interfacial solar heat localization as a high-efficiency approach to desalination. However, the challenge remains to prevent salt accumulation while simultaneously maintaining heat localization. This paper presents an experimental demonstration of a salt-rejecting evaporation structure that can operate continuously under sunlight to generate clean vapor while floating in a saline body of water such as an ocean. The evaporation structure is coupled with a low-cost polymer film condensation cover to produce freshwater at a rate of 2.5 L m−2 day−1, enough to satisfy individual drinking needs. The entire system's material cost is $3 m−2 – over an order of magnitude lower than conventional solar stills, does not require energy infrastructure, and can provide cheap drinking water to water-stressed and disaster-stricken communities.
Physical mechanisms unique to plasmonic materials, which can be exploited for the existing and emerging applications of plasmonics for renewable energy technologies, are reviewed. The hybrid nature of surface plasmon (SP) modes - propagating surface plasmon polaritons (SPPs) and localized surface plasmons (LSPs) - as collective photon-electron oscillations makes them attractive candidates for energy applications. High density of optical states in the vicinity of plasmonic structures enhances light absorption and emission, enables localized heating, and drives near-field heat exchange between hot and cold surfaces. SP modes channel the energy of absorbed photons directly to the free electrons, and the generated hot electrons can be utilized in thermoelectric, photovoltaic and photo-catalytic platforms. Advantages and disadvantages of using plasmonics over conventional technologies for solar energy and waste heat harvesting are discussed, and areas where plasmonics is expected to lead to performance improvements not achievable by other methods are identified.Comment: 25 pages, 8 figures Materials Today, 201
Steam generation using solar energy provides the basis for many sustainable desalination, sanitization, and process heating technologies. Recently, interest has arisen for low-cost floating structures that absorb solar radiation and transfer energy to water via thermal conduction, driving evaporation. However, contact between water and the structure leads to fouling and pins the vapour temperature near the boiling point. Here we demonstrate solar-driven evaporation using a structure not in contact with water. The structure absorbs solar radiation and re-radiates infrared photons, which are directly absorbed by the water within a sub-100 μm penetration depth. Due to the physical separation from the water, fouling is entirely avoided. Due to the thermal separation, the structure is no longer pinned at the boiling point, and is used to superheat the generated steam. We generate steam with temperatures up to 133 °C, demonstrating superheated steam in a non-pressurized system under one sun illumination.
23 October 2017 in Advances in Optics and Photonics
Unlike conventional optics, plasmonics enables unrivaled concentration of optical energy well beyond the diffraction limit of light. However, a significant part of this energy is dissipated as heat. Plasmonic losses present a major hurdle in the development of plasmonic devices and circuits that can compete with other mature technologies. Until recently, they have largely kept the use of plasmonics to a few niche areas where loss is not a key factor, such as surface-enhanced Raman scattering and biochemical sensing. Here, we discuss the origin of plasmonic losses and various approaches to either minimize or mitigate them based on understanding of fundamental processes underlying surface plasmon modes excitation and decay. Along with the ongoing effort to find and synthesize better plasmonic materials, optical designs that modify the optical powerflow through plasmonic nanostructures can help in reducing both radiative damping and dissipative losses of surface plasmons. Another strategy relies on the development of hybrid photonic–plasmonic devices by coupling plasmonic nanostructures to resonant optical elements. Hybrid integration not only helps to reduce dissipative losses and radiative damping of surface plasmons, but also makes possible passive radiative cooling of nanodevices. Finally, we review emerging applications of thermoplasmonics that leverage Ohmic losses to achieve new enhanced functionalities. The most successful commercialized example of a loss-enabled novel application of plasmonics is heat-assisted magnetic recording. Other promising technological directions include thermal emission manipulation, cancer therapy, nanofabrication, nanomanipulation, plasmon-enabled material spectroscopy and thermo-catalysis, solar water treatment, and thermophotovoltaics.