Excellent performances in barrier properties against both oxygen and water vapor have been obtained in poly(propylene 2,5-furandicarboxylate) by forcing crystallization under appropriate conditions.
Nowadays the issues related to the end of life of traditional plastics are very urgent due to the important pollution problems that plastics have caused. Biodegradable plastics can help to try to mitigate these problems, but even bioplastics need much attention to carefully evaluate the different options for plastic waste disposal. In this Minireview, three different end‐of‐life scenarios (composting, recycling, and upcycling) were evaluated in terms of literature review. As a result, the ability of bioplastics to be biodegraded by composting has been related to physical variables and materials characteristics. Hence, it is possible to deduce that the process is mature enough to be a good way to minimize bioplastic waste and valorize it for the production of a fertilizer. Recycling and upcycling options, which could open up many interesting new scenarios for the production of high‐value materials, are less studied. Research in this area can be strongly encouraged.
A new method for the synthesis of polyesters that combines the chemical recycling of poly(ethylene terephthalate) (PET) with the use of monomers derived from renewable resources, such as isosorbide and succinic acid, has been developed. A kinetic study has been performed in order to determine the best catalyst for PET depolymerisation with isosorbide and for the subsequent polycondensation of PET oligomers with succinic acid. Using the correct amounts of isosorbide and succinic acid it is possible to obtain polymers which well fit the properties (glass transition temperature and end-group composition) necessary for powder coating applications. The coating produced using this new environmentally friendly approach presents applicative properties similar, and in some cases superior, to those of a commercial coating obtained from non-renewable resources.
24 June 2008 in Macromolecular Chemistry and Physics