This paper provides a detailed, thorough analysis of air pollution by benzo[a]pyrene (BaP) in the Czech Republic. The Czech residential sector is responsible for more than 98.8% of BaP, based on the national emission inventory. According to the data from 48 sites of the National Air Quality Monitoring Network, the range of annual average concentration of BaP ranges from 0.4 ng·m⁻³ at a rural regional station to 7.7 ng·m⁻³ at an industrial station. Additionally, short-term campaign measurements in small settlements have recorded high values of daily benzo[a]pyrene concentrations (0.1–13.6 ng·m⁻³) in winter months linked to local heating of household heating. The transboundary contribution to the annual average concentrations of BaP was estimated by the CAMx model to range from 46% to 70% over most of the country. However, the contribution of Czech sources can exceed 80% in residential heating hot spots. It is likely that the transboundary contribution to BaP concentrations was overestimated by a factor of 1.5 due to limitations of the modeling approach used. During the period of 2012–2018, 35–58% of the urban population in the Czech Republic were exposed to BaP concentrations above target. A significant decreasing trend, estimated by the Mann-Kendall test, was found for annual and winter BaP concentrations between 2008 and 2018.

The satellite based monitoring initiative for regional air quality (SAMIRA) initiative was set up to demonstrate the exploitation of existing satellite data for monitoring regional and urban scale air quality. The project was carried out between May 2016 and December 2019 and focused on aerosol optical depth (AOD), particulate matter (PM), nitrogen dioxide (NO₂), and sulfur dioxide (SO₂). SAMIRA was built around several research tasks: 1. The spinning enhanced visible and infrared imager (SEVIRI) AOD optimal estimation algorithm was improved and geographically extended from Poland to Romania, the Czech Republic and Southern Norway. A near real-time retrieval was implemented and is currently operational. Correlation coefficients of 0.61 and 0.62 were found between SEVIRI AOD and ground-based sun-photometer for Romania and Poland, respectively. 2. A retrieval for ground-level concentrations of PM_2.5 was implemented using the SEVIRI AOD in combination with WRF-Chem output. For representative sites a correlation of 0.56 and 0.49 between satellite-based PM_2.5 and in situ PM_2.5 was found for Poland and the Czech Republic, respectively. 3. An operational algorithm for data fusion was extended to make use of various satellite-based air quality products (NO₂, SO₂, AOD, PM_2.5 and PM₁₀). For the Czech Republic inclusion of satellite data improved mapping of NO₂ in rural areas and on an annual basis in urban background areas. It slightly improved mapping of rural and urban background SO₂. The use of satellites based AOD or PM_2.5 improved mapping results for PM_2.5 and PM₁₀. 4. A geostatistical downscaling algorithm for satellite-based air quality products was developed to bridge the gap towards urban-scale applications. Initial testing using synthetic data was followed by applying the algorithm to OMI NO₂ data with a direct comparison against high-resolution TROPOMI NO₂ as a reference, thus allowing for a quantitative assessment of the algorithm performance and demonstrating significant accuracy improvements after downscaling. We can conclude that SAMIRA demonstrated the added value of using satellite data for regional- and urban-scale air quality monitoring.