At present, high-damping rubber materials, widely used in the field of engineering seismic isolation, generally have the problems such as narrow effective damping temperature range, low damping loss factor and strong temperature dependence, which lead to prominent dependence of temperature and load conditions of the isolation performance of high-damping rubber isolation bearings. Research and development of high-performance high-damping rubber materials with broad effective damping temperature range, high damping loss factor and weak temperature dependence are very urgent and necessary to ensure the safety of the seismic isolation of engineering structures. This paper mainly reviews the recent progress in the research and development of high-damping rubber materials using nitrile butadiene rubber (NBR), epoxidized natural rubber (ENR), ethylene propylene diene rubber (EPDM), butyl rubber (IIR), chlorinated butyl rubber (CIIR), and bromine butyl rubber (BIIR). This is followed by a review of vulcanization and filler reinforcement systems for the improvement of damping and mechanical properties of high-damping rubber materials. Finally, it further reviews the constitutive models describing the hyperelasticity and viscoelasticity of rubber materials. In view of this focus, four key issues are highlighted for the development of high-performance high-damping rubber materials used for high-damping rubber isolation bearings.

The Hall-Héroult process uses prebaked carbon anodes as electrodes. The anode’s quality plays a crucial role in the efficiency of the aluminium production process. During the baking process, the anode undergoes complex physicochemical transformations. Thus, the production of high-quality anodes depends, among others, on the efficient control of their baking process. This paper aims to investigate the evolution of some physical properties of the anode paste mixture during the baking process. These properties include the mass loss fraction, real and apparent densities, the ratio of apparent volume, the permeability, and porosities. For this purpose, experiments consisting of thermogravimetric analysis, dilatometry, air permeability, and helium-pycnometric measurements were carried out. The anode permeability at high temperatures was linked to the air permeability through a permeability correlator due to experimental limitations. Moreover, the real density at high temperatures was estimated by combining real densities of the coal tar pitch and coke aggregates. Different porosities, such as the open porosity and the closed porosity related to the pitch binder, were estimated by taking the permeability at high temperatures into account. In this context, the effect of the permeability correlator, which was introduced to link the permeability at high temperatures to the air permeability, was investigated through a sensitivity analysis. These results allow an estimation of the shrinking index, a new variable introduced to reflect the baking level of the anode mixture, which is linked to the volatile that is released in both open and closed pores. Afterwards, the pore pressure inside closed pores in the coal tar pitch was estimated. The obtained results highlight some new insights related to the baking process of the anode mixture. Moreover, they pave the way for better modeling of the thermo-chemo-mechanical behavior of anodes at high temperatures.

With the rapid development of the economy and urbanization, the construction of the urban rail transit system has had a great impact on the work, life, and health of residents in buildings along the rail transit line. Thus, it is particularly urgent and necessary to develop base isolation technologies to control and reduce the impact of vibrations of rail transit systems on building structures. High-damping rubber isolation bearings have shown significant effectiveness in the reduction of this impact, and their isolation performance mainly depends on the mechanical and damping energy dissipation characteristics of the high-damping rubber material. This paper aims to investigate the hyper-viscoelastic properties of the high-damping rubber material used for high-damping rubber isolation bearings during the cyclic tension and compression process in the vertical direction. These properties include hyperelastic parameters, viscoelastic coefficients, and the relaxation times of the material. For this purpose, uniaxial cyclic tension and compression tests were conducted. A three-element Maxwell rheological model combining a strain energy density function was proposed for modeling the hyper-viscoelastic behaviors of the materials during the cyclic tension and compression process. Based on the obtained results, an iterative identification procedure was used to determine the constitutive parameters of the material for each loading-unloading cycle. The aforementioned parameters were further expressed as a function of the number of cycles. New insights into hyper-viscoelastic property changes in this high-damping rubber material during the cyclic tension and compression process were gained in this work. These investigations could facilitate the development of computational tools, which would regulate fundamental guidelines for the better controlling and optimization of the isolation performance of the high-damping rubber material used for high-damping rubber isolation bearings, which have a wider perspective of applications in the urban rail transit system.

In the Hall–Héroult process, prebaked carbon anodes are utilized to produce primary aluminium. The quality of the anode plays a crucial role in the efficiency of electrowinning primary aluminium. In the production of anodes, the anode baking is considered as the stage most frequently causing anode problems. During the baking process, the anode undergoes complex physicochemical transformations. Moreover, the anode at a lower position, imposed by loading pressures from upper anodes, will creep during this process. Thus, the production of high-quality anodes demands efficient control of their baking process. This paper aims to investigate the thermo-chemo-mechanical properties of the anode paste mixture at high temperatures. These properties include kinetic parameters of pitch pyrolysis such as the activation energy and the pre-exponential factor, the thermal expansion coefficient (TEC) and relevant mechanical parameters related to the elastic, the viscoelastic and the viscoplastic behaviours of the anode. For this purpose, experiments consisting of the thermogravimetric analysis, the dilatometry and the creep test were carried out. Based on the obtained results, the forementioned parameters were identified. Relevant mechanical parameters were expressed as a function of a new variable, called the shrinking index, which is related to the volatile released in open and closed pores of the anode. This variable would be used to highlight the chemo-mechanical coupling effect of the anode mixture. New insights into the phenomena such as the expansion due to the increase of the pore pressure and the chemical shrinkage of the anode during the baking process were also gained in this work. These investigations pave the way for modeling the thermo-chemo-poromechanical behaviour of the anode during the baking process.

Aluminum is reduced from alumina by the Hall–Héroult electrolysis process in which the anode is utilized as the positive electrode. The quality of the prebaked anode plays a crucial rule in the efficiency of the aluminum electrolysis process. To produce high-quality anodes in the aluminum industry, the anode baking process calls for a deep understanding of mechanisms that govern the evolution of the anode mixture properties under the high-temperature condition. Therefore, the aim of this paper is to establish a thermo-chemo-poromechanical model for the baking anode by using the theory of reactive porous media based on the theory of mixtures within the thermodynamic framework. For this purpose, an internal state variable called “shrinking index” is defined to characterize the chemical progress of the pitch pyrolysis in the anode skeleton, and the Clausius–Duhem inequality is developed according to the Lagrangian formalism. By introducing a reduced Green–Lagrange strain tensor, a Lagrangian free energy is formulated to found a set of state equations. Then, the thermodynamic dissipation for this pyrolyzing solid–gas mixture is derived, and a constitutive model linking the chemical pyrolysis with the mechanical behavior is achieved. A dissipation potential is consistently defined to ensure the non-negativeness of the thermodynamic dissipation and to obtain the constitutive laws for viscous behaviors. Field equations governing the volatile diffusion and the heat transfer through the draining mixture body are derived from the entropy balance.