The Lithium-ion battery (LIB) is an important technology for the present and future of energy storage, transport, and consumer electronics. However, many LIB types display a tendency to ignite or release gases. Although statistically rare, LIB fires pose hazards which are significantly different to other fire hazards in terms of initiation route, rate of spread, duration, toxicity, and suppression. For the first time, this paper collects and analyses the safety challenges faced by LIB industries across sectors, and compares them to the research contributions found in all the review papers in the field. The comparison identifies knowledge gaps and opportunities going forward. Industry and research efforts agree on the importance of understanding thermal runaway at the component and cell scales, and on the importance of developing prevention technologies. But much less research attention has been given to safety at the module and pack scales, or to other fire protection layers, such as compartmentation, detection or suppression. In order to close the gaps found and accelerate the arrival of new LIB safety solutions, we recommend closer collaborations between the battery and fire safety communities, which, supported by the major industries, could drive improvements, integration and harmonization of LIB safety across sectors.

Smouldering combustion is the driving phenomenon of wildfires in peatlands, and is responsible for large amounts of carbon emissions and haze episodes world wide. Compared to flaming fires, smouldering is slow, low-temperature, flameless, and most persistent, yet it is poorly understood. Peat, as a typical organic soil, is a porous and charring natural fuel, thus prone to smouldering. The spread of smouldering peat fire is a multidimensional phenomenon, including two main components: in-depth vertical and surface lateral spread. In this study, we investigate the lateral spread of peat fire under various moisture and wind conditions. Visual and infrared cameras as well as a thermocouple array are used to measure the temperature profile and the spread rate. For the first time the overhang, where smouldering spreads fastest beneath the free surface, is observed in the laboratory, which helps understand the interaction between oxygen supply and heat losses. The periodic formation and collapse of overhangs is observed. The overhang thickness is found to increase with moisture and wind speed, while the spread rate decreases with moisture and increases with wind speed. A simple theoretical analysis is proposed and shows that the formation of overhang is caused by the spread rate difference between the top and lower peat layers as well as the competition between oxygen supply and heat losses

Carbon-rich soils, like histosols or gelisols, cover more than 3% of the Earth's land surface, and store roughly three times more carbon than the Earth's forests. Carbon-rich soils are reactive porous materials, prone to smouldering combustion if the inert and moisture contents are low enough. An example of soil combustion happens in peatlands, where smouldering wildfires are common in both boreal and tropical regions. This work focuses on understanding soil ignition by self-heating, which is due to spontaneous exothermic reactions in the presence of oxygen under certain thermal conditions. We investigate the effect of soil inorganic content by creating under controlled conditions soil samples with inorganic content (IC) ranging from 3% to 86% of dry weight: we use sand as a surrogate of inorganic matter and peat as a surrogate of organic matter. This range is very wide and covers all IC values of known carbon-rich soils on Earth. The experimental results show that self-heating ignition in different soil types is possible, even with the 86% inorganic content, but the tendency to ignite decreases quickly with increasing IC. We report a clear increase in ambient temperature required for ignition as the IC increases. Combining results from 39 thermostatically-controlled oven experiments, totalling 401 h of heating time, with the Frank-Kamenetskii theory of ignition, the lumped chemical kinetic and thermal parameters are determined. We then use these parameters to upscale the laboratory experiments to soil layers of different thicknesses for a range of ambient temperatures ranging from 0 °C to 40 °C. The analysis predicts the critical soil layer thicknesses in nature for self-ignition at various possible environmental temperatures. For example, at 40 °C a soil layer of 3% inorganic content can be ignited through self-heating if it is thicker than 8.8 m, but at 86% IC the layer has to be 1.8 km thick, which is impossible to find in nature. We estimate that the critical IC for a ambient temperature of 40 °C and soil thickness of 50 m is 68%. Because those are extreme values of temperature and thickness, no self-heating ignition of soil can be expected above the 68% threshold of inorganic content. This is the first in-depth experimental quantification of soil self-heating and shows that indeed it is possible that wildfires are initiated by self-heating in some soil types and conditions