Cherts have been thought to originate from biosilicification, terrestrial inputs and hydrothermal activity. The study of cherts is helpful in understanding the paleo-ocean environment and tectonic–sedimentary processes. Large amounts of cherts occur widely in the Maokou Formation in the Sichuan Basin, which may be largely connected to the Permian Chert Event (PCE). However, the source of silica and the formation process of cherts remain debated. Here, we analyze the petrographic and geochemical features of the cherts from the Guadalupian Maokou Formation (~268–259 Ma) in six sections in the Sichuan Basin. Two main types of cherts, nodular and bedded, are recognized in the Maokou Formation. The formation of nodular cherts was mainly affected by hydrothermal fluids, whereas the bedded cherts are mainly of biogenetic origin. The Emeishan large igneous province (ELIP) caused the activation of deep faults, accompanied by intense hydrothermal activities. Correspondingly, the cherts of significant hydrothermal origin developed near the active deep faults. The intensified hydrothermal activities may provide extra silica supplies and flourish the silica-secreting organisms by the associated volcanogenic upwellings that facilitated the enrichment of cherts. The study of Maokou cherts can help to record the volcanic- and silicon-related biological activities in the eastern Paleo-Tethys Ocean and can provide significant implications for chert enrichment in analogous settings.

In recent years, the discovery of two gas fields in the fourth member of the Leikoupo Formation in the Western Sichuan Basin of SW China confirmed the exploration potential of microbial carbonates. The aim of the present study is to clarify the formation mechanism of the microbial reservoirs in the Leikoupo Formation. For this purpose, lithofacies, depositional environments, and diagenesis analyses were performed in samples collected from cores of 12 wells. The climate of study area was arid during Anisian time, and the water body was restricted. In such a climate, an evaporitic environment was developed, where ten types of lithofacies, dominated by microbial carbonates and gypsum rocks, were recognized. Thrombolites and stromatolites are the main high-quality reservoirs rock types in the fourth member of the Leikoupo Formation in the Western Sichuan Basin of SW China, which developed as microbial mounds, with reservoir space of microbial inter-clot pores, intra-clot pores, fenestral pores, inter-crystalline pores, and cracks. The microbial inter-clot pores are the main reservoir space, formed by trapping and binding of marls by benthic microbial communities. These pores were partially filled with evaporites because of the arid climate, which were subsequently dissolved (mainly gypsum) in the syn-depositional period, thus greatly improving the quality of reservoirs. Although some pores were occluded by multi-stage cements during the burial stage, major pores were well preserved own to the early dolomitization, rapid burial of the Leikoupo Formation, and early charging of hydrocarbon. The early dolomitization enhanced the anti-compaction ability of microbial carbonates during the burial stage. Rapid burial of the Leikoupo succession slowed down early cementation, and it also accelerated the maturation and expulsion process source rock to promote early charging of hydrocarbon in pores, which created a closed system, inhibiting strong burial cementation.

Dolomite bodies in the Middle Permian of the central Sichuan Basin have been reported as favorable natural gas reservoirs. The Middle Permian dolomite consists of three types of recrystallized dolomite (Rd1, Rd2, and Rd3) and one type of dolomite cement (Sd). Rd1 might be formed as the primary mineral along the calcite in the original sea-water. Its δ¹³C value and ⁸⁷Sr/⁸⁶Sr ratio, consistent with those of marine limestone and Permian seawater, support that the dolomitizing fluid for Rd1 was Permian seawater preserved in the strata. Rd2 consists of fine to medium (50 μm to 250 μm) and planar to curved crystals. Geochemical indicators (slightly high ⁸⁷Sr/⁸⁶Sr ratio, similar rare earth element patterns, negative δ¹⁸O, slightly high salinity) confirm that the dolomitizing fluid of Rd2 was mainly Permian seawater during shallow burial, with a small number of hydrothermal fluids. Rd3 and Sd are featured by very large (>250 μm), curved crystals, and high-temperature, high-salinity, and obviously positive Eu anomalies, suggesting that their diagenetic fluids were mainly hydrothermal fluids from deep. Additionally, inherited carbon sources and the ⁸⁷Sr/⁸⁶Sr ratios of some samples fall within the range of Permian seawater distribution, confirming the contribution of Permian seawater. ELIP activity caused the formation of this dolomite through the mixing of seawater and hydrothermal fluids. The main fluid circulation channels were activated basement faults, epigenetic karst pores, and shallowly buried high-permeability strata. During the peak period of ELIP activity, the continuous upwelling of deep hydrothermal fluids led to the continuous formation of Rd2, Rd3, and Sd. The dolomitization fluid of Rd2 was mainly composed of seawater and featured a certain lateral extension, which was away from faults. Rd3 and Sd are mainly distributed along the fault system, and excessive dolomitization caused by the hydrothermal activity, to some extent, inhibited the lateral movement of hydrothermal fluids. This study provides a good example for exploring the genetic mechanism and distribution pattern of structurally controlled dolomites under a volcanic activity background.

The Sichuan Basin located in the western region of the Yangtze block was a stable craton basin in the Permian. The structural differentiation caused by the Dongwu movement and the Emei rifting activity controlled the sedimentary system and the Permian carbonate gas reservoirs in the Sichuan Basin. In this study, we have investigated the stratigraphic characteristics of each Permian formation, studied the depositional systems of each period of the Permian stage, and discussed the overall tectono-sedimentary evolution of the sedimentary basin. During the Permian, the Sichuan Basin experienced an intense tectonic activity, controlling the variations of the sedimentary environments occurring in the basin. The depositional systems of the basin were controlled by the tectonic setting of the intra-cratonic depression and marginal rifts during the period. Therefore, this is an important period in the tectono-sedimentary evolution of the study area, which can be divided into the following stages: (1) From the Late Carboniferous to the Early Permian, the Sichuan Basin was dominated by tectonic uplift and denudation. In the Middle Permian, a regional transgression occurred in the whole upper Yangtze region, and the sedimentary environments of the Sichuan Basin and its adjacent areas gradually changed to the carbonate platform. (2) In the early phase of the Late Permian (the Wujiaping period), being influenced by the Emei rift, the Sichuan Basin and its adjacent areas formed a complex pattern of structural highs and adjacent depressions, controlled by a differential subsidence. (3) In the late phase of the Late Permian (the Changxing period), with the cessation of the volcanic activity and the enhancement of the regional extension, the pattern of structural highs and depressions is more obvious, and the relatively calm structural environment makes the carbonate sedimentary environment tending to dominate.