The urban alternate water source (AWS) is of great significance to the sustainable development of the city, the pollution degree, and source of heavy metals (HMs) in AWS, and whether it will adversely affect human health has received widespread attention. In this study, the urban AWS of Xinbian River in Suzhou City, Huaibei Plain, China, was used as the research object to study the seasonal changes of HMs (As, Cr, Cu, Cd, Pb, and Zn), quantitative identification of pollution sources, and human health risks (HHR). Research results show that the contents of those HMs, except As, are less than the drinking standards limit set by the World Health Organization (WHO), and the contents of As, Cr, and Zn are the largest in summer. The multivariate statistical analysis combined with positive matrix factorization (PMF) model analysis revealed that industrial sources accounted for 44.83%, and agricultural sources accounted for 55.17%. HHR assessment based on Monte Carlo simulation shows that the noncarcinogenic risks of adults and children are in the acceptable range (hazardous ingestion (HI) < 1), and the probability of carcinogenic risk values of children and adults are 95.03% and 38.96%, respectively, which are exceed the acceptable range (1 × 10^-4) recommended by the United States Environment Protection Agency (USEPA). Approximately 30.75% of the carcinogenic risk value of agricultural source HMs to children exceeds the acceptable range (1 × 10^-4). The above research results indicate that the effect of agricultural non-point source pollution on AWS should be prevented.

Developing cost-effective Pt-based electrocatalysts for a highly efficient hydrogen evolution reaction (HER) is of paramount significance for future renewable energy. Herein, we report a new strategy to support sub-1 nm Pt nanoclusters on N and P co-doped carbon nanotubes (NP-CNTs). The prepared Pt/NP-CNT catalyst with an average Pt nanocluster size of 0.65 nm and a Pt loading of 1.4 wt% exhibits outstanding HER performance, in terms of negligible onset potential, 25 mV overpotential to reach 10 mA cm⁻², a low Tafel slope of 28 mV dec⁻¹, and excellent durability for more than 20 h without deactivation. This study provides an avenue for designing efficient and cost-effective Pt-based electrocatalysts for the production of high-purity hydrogen energy by water electrolysis.