In the context of hydrogen production from biomass or organic waste with dark fermentation, this study analysed 55 studies (339 experiments) in the literature looking for the effect of operating parameters on the process performance of dark fermentation. The effect of substrate concentration, pH, temperature, and residence time on hydrogen yield, productivity, and content in the biogas was analysed. In addition, a linear regression model was developed to also account for the effect of nature and pretreatment of the substrate, inhibition of methanogenesis, and continuous or batch operating mode. The analysis showed that the hydrogen yield was mainly affected by pH and residence time, with the highest yields obtained for low pH and short residence time. High hydrogen productivity was favoured by high feed concentration, short residence time, and low pH. More modest was the effect on the hydrogen content. The mean values of hydrogen yield, productivity, and content were, respectively, 6.49% COD COD⁻¹, 135 mg L⁻¹ d⁻¹, 51% v/v, while 10% of the considered experiments obtained yield, productivity, and content of or higher than 15.55% COD COD⁻¹, 305.16 mg L⁻¹ d⁻¹, 64% v/v. Overall, this study provides insight into how to select the optimum operating conditions to obtain the desired hydrogen production.

The feasibility of producing activated carbon (AC) from real Household Mixed Plastic Waste (HMPW) comprising of LDPE, HDPE, PP, PS, and PET for carbon capture via direct carbonisation followed by microwave-assisted or conventional thermally assisted chemical activation was investigated. A microwave-assisted activation procedure was adopted to assess the impact on the CO₂ capture capacity of the resulting AC using both a lower temperature (400 °C vs. 700 °C) and a shorter duration (5 vs. 120 mins) than that required for conventional activation. The results obtained showed that the AC yield was 71 and 78% for the conventional and microwave-assisted samples, respectively. Microwave activation consumed five-fold less energy (0.19 kWh) than the conventional activation (0.98 kWh). Thermal stability results indicated total weight loss of 10.0 and 8.3 wt%, respectively, for conventional and microwave-activated samples over the temperature range of 25-1000 °C, with ACs from both activation routes displaying a type 1 nitrogen isotherm. The dynamic CO₂ uptake capacity at 1 bar and 25 °C was 1.53 mmol/g, with maximum equilibrium uptake ranging between 1.32 and 2.39 mmol/g at temperatures (0-50 °C) and 1 bar for the conventionally activated AC. The analogous microwave-activated sample showed a higher dynamic CO₂ uptake of 1.62 mmol/g and equilibrium uptake in the range 1.58-2.88 mmol/g under equivalent conditions. The results therefore indicate that microwave activation results in enhanced carbon capture potential. To the best of our knowledge, this is the first-time microwave heating has been employed to convert household mixed plastic wastes directly into ACs for carbon capture applications. This report therefore demonstrates that the management of mixed plastics could lead to the development of a circular economy through the conversion of waste into value-added materials.