A bimetallic pentadecanuclear cyanido-bridged {Fe₉[W(CN)₈]₆ (MeOH)₂₄}·xMeOH cluster of an Fe^II/III–W^IV/V mixed valence nature, reveals a reversible single-crystal-to-single-crystal transformation, concomitant with metal-to-metal charge transfer between Fe and W ions. The dominance of ^HSFe^II–NC–W^V units at a high temperature, and ^HSFe^III–NC–W^IV units at a low temperature, leads to an unprecedented reversed thermal hysteresis loop in magnetic measurements.

Features of glass transition in liquid crystalline nematic and smectic E, B and I_A phases of selected materials observed by means of the polarising microscopy and Fourier transform infrared spectroscopy (FTIR) are reported. Evolution of cracking in the glass and a coincidence of its disappearance temperature with the glass transition temperature (T_g) on heating is shown and discussed in the context of processes that occur in the glass. The shape of temperature dependencies of absorption bands is shown as the signature of the glass transition.

The kinetics of the non-isothermal and isothermal crystallization of the crystalline smectic B phase (soft crystal B, SmB_cr) in 4-n-butyloxybenzylidene-4′-n′-octylaniline (BBOA) was studied by a combination of differential scanning calorimetry (DSC), broadband dielectric spectroscopy (BDS) and polarized optical microscopy (POM). On cooling, part of the SmB_cr phase undergoes conversion to a crystalline phase and the remainder forms a glassy state; after the glass softens, crystallization is completed during subsequent heating. By analyzing the area of the crystal growing in the texture of SmB_cr as a function of time, the evolution of degree of crystallinity, D(t), was estimated. It was demonstrated that upon heating, D(t) follows the same Avrami curve as the crystallization during cooling. Non-isothermal crystallization observed during slow cooling rates (3K/min ≤ ϕ ≤ 5K/min) is a thermodynamically-controlled process with the energy barrier Ea ≈ 175 kJ/mol; however, the crystallization occurring during fast cooling (5 K/min > ϕ ≥ 30K/min) is driven by a diffusion mechanism, and is characterized by E_a ≈ 305 kJ/mol. The isothermal crystallization taking place in the temperature range 274 K and 281 K is determined by nucleus formation.