Metal-halide perovskites have rapidly emerged as one of the most promising materials of the 21st century, with many exciting properties and great potential for a broad range of applications, from photovoltaics to optoelectronics and photocatalysis. The ease with which metal-halide perovskites can be synthesized in the form of brightly luminescent colloidal nanocrystals, as well as their tunable and intriguing optical and electronic properties, has attracted researchers from different disciplines of science and technology. In the last few years, there has been a significant progress in the shape-controlled synthesis of perovskite nanocrystals and understanding of their properties and applications. In this comprehensive review, researchers having expertise in different fields (chemistry, physics, and device engineering) of metal-halide perovskite nanocrystals have joined together to provide a state of the art overview and future prospects of metal-halide perovskite nanocrystal research.
We report the first experimental realization of a three-dimensional thermal cloak shielding an air bubble in a bulk metal without disturbing the external conductive thermal flux. The cloak is made of a thin layer of homogeneous and isotropic material with specially designed three-dimensional manufacturing. The cloak's thickness is $100\text{ }\text{ }$\mu${}\mathrm{m}$ while the cloaked air bubble has a diameter of 1 cm, achieving the ratio between dimensions of the cloak and the cloaked object 2 orders smaller than previous thermal cloaks, which were mainly realized in a two-dimensional geometry. This work can find applications in novel thermal devices in the three-dimensional physical space.
In the most recent decade, carbon dots have drawn intensive attention and triggered substantial investigation. Carbon dots manifest superior merits, including excellent biocompatibility both in vitro and in vivo, resistance to photobleaching, easy surface functionalization and bio-conjugation, outstanding colloidal stability, eco-friendly synthesis, and low cost. All of these endow them with the great potential to replace conventional unsatisfactory fluorescent heavy metal-containing semiconductor quantum dots or organic dyes. Even though the understanding of their photoluminescence mechanism is still controversial, carbon dots have already exhibited many versatile applications. In this article, we summarize and review the recent progress achieved in the field of carbon dots, and provide a comprehensive summary and discussion on their synthesis methods and emission mechanisms. We also present the applications of carbon dots in bioimaging, drug delivery, microfluidics, light emitting diode (LED), sensing, logic gates, and chiral photonics, etc. Some unaddressed issues, challenges, and future prospects of carbon dots are also discussed. We envision that carbon dots will eventually have great commercial utilization and will become a strong competitor to some currently used fluorescent materials. It is our hope that this review will provide insights into both the fundamental research and practical applications of carbon dots.