Nutrient availability after fertilising agricultural soils is affected by many factors, including soil moisture conditions and physicochemical properties. Herein, the availability of potassium in soil enriched with biochar is studied, considering either saturated or unsaturated moisture conditions and questioning key ion exchange approaches, such as equilibrium exchange (E.E.) and kinetic exchange (K.E.). Potassium release is simulated from a soil–biochar mixture of 0, 0.5, 1 and 2% by coupling HYDRUS-1D and PHREEQC models. The water flow, mass transport and geochemical processes are simulated for a cultivation period that imitates agronomic and environmental conditions of a common agricultural field in Northern Greece. Potassium is released gradually during the irrigation period in the case of unsaturated flow conditions as opposed to its complete release over a few days in the case of saturated flow conditions in the soil. Regarding ion-exchange processes, the soluble amount of potassium is more readily available for transport in soil solution when using the E.E. approach compared to the K.E. approach that assumes a kinetically controlled release due to interactions occurring at the solid–solution interface. The increased proportion of biochar in soil results in a doubling of available potassium. Among the four modelling schemes, although the total mass of potassium released into soil solution is similar, there is a significant variation in release time, indicating that simplified saturated conditions may lead to unrealistic estimates of nutrient availability. Further experimental work will be valuable to decrease the uncertainty of model parameter estimation in the K.E. approach.

Olive mill wastes continue to be a management challenge due to the large volumes produced, particularly due to their toxicity and impacts on the environment. Thermal conversion through pyrolysis or hydrothermal carbonization techniques can detoxify wastes while conserving nutrient contents. In this work, we produced up-to-date data on olive mill waste flows in Spain, Tunisia, and Greece and characterized representative samples in the laboratory. Assays of thermal conversion of olive mill wastewaters and solid wastes were also performed to understand biochar yields and final properties, and the total quantities of nutrients contained were estimated. Of particular note were the quantities of potassium in Tunisian wastewaters, representing 0.6% of the total mass and an annual flow of approximately 5000 t, and in the Spanish solid wastes, an average of 1.7% of the total mass is potassium, representing an annual flow of approximately 23,000 t. Concerning phosphorus, Spanish solid wastes had the highest contents (0.1%), double that of other countries’ wastes. Annually, olive mill wastes from the three countries are estimated to contain approximately 35 × 10³ tons of potassium and 2.6 × 10³ tons of phosphorus. With this resource converted to biochar, each year more than 700 km² of soils could be enriched in 0.2% carbon with biochar at an application rate of 7 t ha⁻¹.

This work examines in silico the dominant geochemical processes that control inorganic nutrients (Ca, Mg, Na, K) availability in irrigated agricultural soil amended with potassium-enriched biochar (from olive mill wastes) at mass doses of 0.5%, 1%, 2% and 10%. The geochemical modelling step was supported by analytical measurements regarding the physicochemical characteristics of the irrigation water, the agricultural soil and the biochar. Two geochemical approaches, namely equilibrium exchange (E.E.) and kinetic exchange (K.E.) models were applied and compared to assess nutrient release with an emphasis on potassium availability. Equilibrium exchange perspective assumed that nutrient release is controlled by ion-exchange reactions onto the biochar surface, whilst kinetic exchange perspective assumed the contribution of both ion-exchange and dissolution of salts. Results indicated that for the E.E. model, the soluble amount of potassium is readily available for transport within the pores of the porous media, and therefore is leached from the column within only 10 days. For the K.E. model that assumes a kinetically controlled release of potassium due to interactions occurring at the solid-solution interface, the assessed retention times were more realistic and significantly higher (up to 100 days). Concerning the applied doses of biochar, for a 2% biochar fraction mixed with soil, for example, the available K for plants doubled compared with the available K in the soil without biochar. In any case, the use of numerical modeling was proven helpful for a quick assessment of biochar performance in soil, by avoiding time-consuming and laborious experimental set-ups. Validation of the models by experimental data will further establish the proposed mechanisms.

The accelerated climate crisis has exacerbated the existing water and soil management challenges in the Mediterranean region, which are usually attributed to the combination of both irrational irrigation and unsustainable farming practices. The current conditions and future projections indicate that water-related risks are expected to intensify during the coming decades. Moreover, farmers often do not possess high environmental awareness; they adopt non-sustainable farming practices such as the extensive use of herbicides instead of mowing/mulching for the weeds, thus affecting soil hydraulic characteristics and fertility. To investigate the effects of different weed-management practices on soil organic carbon and thus on soil water holding capacity and infiltrability, an extensive soil-sampling campaign was performed in the semi-arid Mediterranean agricultural pilot basin of Agia—Greece. The pilot is located in the Pinios river basin, which constitutes the most highly productive agricultural plain in the country. The Agia basin was selected since it presents the uneven spatiotemporal distribution of groundwater resources and the wide application of herbicides, while an urgent need exists to sustain and improve agricultural production, with the main crops being apples and cherries. Moreover, the Agia basin constitutes a highly instrumented area where the Pinios Hydrologic Observatory belonging to the International Long Term Ecological Research network has been developed, and thus additional field measurements could contribute to the overall data-collection framework. Soil sampling was conducted in apple orchards in April 2022, just before the beginning of the growing season. Ninety six soil samples in total were collected from eight different fields; half of them applied systematic herbicides treatment, and others mulching. For the upper soil profile (0–10 cm depth), the results indicate that soil organic carbon in the fields applying mowing was found to be higher by more than 30% compared to the fields applying herbicides. The corresponding difference for soil depth of 10–30 cm was 7%, thus demonstrating the effectiveness of mulching in increasing soil organic carbon. The results of the current study could be upscaled at a larger scale in the context of adapting agricultural water-stressed regions to climate change, whilst contributing significantly to the production cost and the preservation of the ecosystemic values of the regional nexus.