Carbon (C) is a crucial material for many branches of modern technology. A growing number of demanding applications in electronics and telecommunications rely on the unique properties of C allotropes. The need for microwave absorbers and radar-absorbing materials is ever growing in military applications (reduction of radar signature of aircraft, ships, tanks, and targets) as well as in civilian applications (reduction of electromagnetic interference among components and circuits, reduction of the back-radiation of microstrip radiators). Whatever the application for which the absorber is intended, weight reduction and optimization of the operating bandwidth are two important issues. A composite absorber that uses carbonaceous particles in combination with a polymer matrix offers a large flexibility for design and properties control, as the composite can be tuned and optimized via changes in both the carbonaceous inclusions (C black, C nanotube, C fiber, graphene) and the embedding matrix (rubber, thermoplastic). This paper offers a perspective on the experimental efforts toward the development of microwave absorbers composed of carbonaceous inclusions in a polymer matrix. The absorption properties of such composites can be tailored through changes in geometry, composition, morphology, and volume fraction of the filler particles. Polymercomposites filled with carbonaceous particles provide a versatile system to probe physical properties at the nanoscale of fundamental interest and of relevance to a wide range of potential applications that span radar absorption, electromagnetic protection from natural phenomena (lightning), shielding for particle accelerators in nuclear physics, nuclear electromagnetic pulse protection, electromagnetic compatibility for electronic devices, high-intensity radiated field protection, anechoic chambers, and human exposure mitigation. Carbonaceous particles are also relevant to future applications that require environmentally benign and mechanically flexible materials.
28 October 2009 in Advances in Optics and Photonics
Over the years extensive studies have been carried out to apply coherent optics methods in real-time communications and image transmission. This is especially true when a large amount of information needs to be processed, e.g., in high-resolution imaging. The recent progress in data-processing networks and communication systems has considerably increased the capacity of information exchange. However, the transmitted data can be intercepted by nonauthorized people. This explains why considerable effort is being devoted at the current time to data encryption and secure transmission. In addition, only a small part of the overall information is really useful for many applications. Consequently, applications can tolerate information compression that requires important processing when the transmission bit rate is taken into account. To enable efficient and secure information exchange, it is often necessary to reduce the amount of transmitted information. In this context, much work has been undertaken using the principle of coherent optics filtering for selecting relevant information and encrypting it. Compression and encryption operations are often carried out separately, although they are strongly related and can influence each other. Optical processing methodologies, based on filtering, are described that are applicable to transmission and/or data storage. Finally, the advantages and limitations of a set of optical compression and encryption methods are discussed.
The challenge of designing new solid-state materials from calculations performed with the help of computers applied to models of spatial randomness has attracted an increasing amount of interest in recent years. In particular, dispersions of particles in a host matrix are scientifically and technologically important for a variety of reasons. Herein, we report our development of an efficient computer code to calculate the effective (bulk) permittivity of two-phase disordered composite media consisting of hard circular disks made of a lossless dielectric (permittivity ) randomly placed in a plane made of a lossless homogeneous dielectric (permittivity ) at different surface fractions. Specifically, the method is based on (i) a finite-element description of composites in which both the host and the randomly distributed inclusions are isotropic phases, and (ii) an ordinary Monte Carlo sampling. Periodic boundary conditions are employed throughout the simulation and various numbers of disks have been considered in the calculations. From this systematic study, we show how the number of Monte Carlo steps needed to achieve equilibrated distributions of disks increases monotonically with the surface fraction. Furthermore, a detailed study is made of the dependence of the results on a minimum separation distance between disks. Numerical examples are presented to connect the macroscopic property such as the effective permittivity to microstructural characteristics such as the mean coordination number and radial distribution function. In addition, several approximate effective medium theories, exact bounds, exact results for two-dimensional regular arrays, and the exact dilute limit are used to test and validate the finite-element algorithm. Numerical results indicate that the fourth-order bounds provide an excellent estimate of the effective permittivity for a wide range of surface fractions, in accordance with the fact that the bounds become progressively narrower as more microstructural information is incorporated. Future directions of the active field of computational studies of the structure-property relations for composite systems are briefly discussed.
This article is devoted to the study of the complex permittivity of two-dimensional two-phase statistically isotropic heterostructures on a small scale such that the quasistatic limit is applicable. Even though several analytical approximation techniques have been developed in the past, today it is desirable to be able to simulate these media via computer, which necessitates the development of efficient numerical techniques for the solution of the resulting equations. The simulation data concern the effective permittivity of continuum composites consisting of distributions of hard disks of a dielectric phase randomly dispersed in a continuous matrix of another dielectric phase. The three-dimensional equivalent of this model would be a composite with cylindrical symmetry, i.e., all interfaces are parallel to a fixed direction. The two constituents are assumed to be isotropic and homogeneous materials with scalar permittivities. Ab initio calculations are accomplished self-consistently with a computer code. The distribution of monodisperse inclusions is equilibrated by the Monte Carlo method and the dielectric study was carried out using the finite element method. Results are first presented documenting the effects of the surface fraction of the disks and the permittivity contrast between the two phases on the complex effective permittivity of the composite material. The numerical results are then compared with available effective medium approaches and bounds methods. The effective complex permittivity is found to lie within the four-point bounds in the complex plane and between the curves corresponding to Maxwell Garnett and asymmetric Bruggeman formulas. The scaling analysis reported here highlights a number of complexities not previously noted for this system. The exponents governing the critical behavior of the real and imaginary parts of the complex permittivity can be quite different from those characterizing the continuum percolation phenomena in a statistically inhomogeneous system of partially penetrable disks.
Electromagnetic (EM) composites have stimulated tremendous fundamental and practical interests owing to their flexible electromagnetic properties and extensive potential engineering applications. Hence, it is necessary to systematically understand the physical mechanisms and design principles controlling EM composites. In this Tutorial, we first provide an overview of the basic theory of electromagnetism about electromagnetic constitutive parameters that can represent the electromagnetic properties of materials. We show how this corpus allows a consistent construction of effective medium theories and allows for numerical simulation of EM composites to deal with structure–property relationships. We then discuss the influence of spatial dispersion of shaped inclusions in the material medium on the EM properties of composites, which has not been systematically illustrated in the context of this interdisciplinary topic. Next, artificial composites or metamaterials with peculiar properties not readily available in nature are highlighted with particular emphasis on the control of the EM interaction with composites. We conclude by discussing appropriate methods of electromagnetic measurement and practical aspects for implementing composites for specific applications are described. Overall, this Tutorial will serve the purpose of introducing the basics and applications of electromagnetic composites to newcomers in this field. It is also anticipated that researchers from different backgrounds including materials science, optics, and electrical engineering can communicate to each other with the same language when dealing with this interdisciplinary subject and further push forward this advancement from fundamental science to technological applications.
An understanding of the polarization characteristics is a prevailing issue in electrostatics and scattering theory and is also vital to the rational design of future dielectric nanostructures. In this work, a finite-element methodology has been applied to simulate two-phase heterostructures containing a polarizable dielectric inclusion. The inclusions investigated can be considered as arbitrarily shaped cross sections of infinite three-dimensional objects, where the properties and characteristics are invariant along the perpendicular cross-sectional plane. Given the paucity of experimental and numerical data, we set out to systematically investigate the trends that shape and permittivity contrast between the inclusion and the host matrix have on the depolarization factor (DF). The effect of the first–versus second-order concentration virial coefficient on the value of the DF is considered for a variety of inclusion shapes and a large set of material properties. Our findings suggest that the DF for such inclusions is highly tunable depending on the choice of these parameters. These results can provide a useful insight for the design of artificial two-phase heterostructures with specific polarization properties.