This article describes the static, dynamic, and temperature dependent magneto‐transport properties of the Fe/BTO/LSMO mutliferroic tunnel junction (MFTJ). The multilayer structure is grown on a high quality crystalline STO substrate by means of pulsed laser deposition, which enables epitaxial layer‐by‐layer growth. The MFTJ is patterned into micrometer‐size devices by means of the ion‐etching‐free lithography process ensuring that the properties of the oxide layers are preserved after the device fabrication. The measured static properties indicate that the MFTJ has multiferroic properties at room temperature with the tunneling electroresistance (TER) and tunneling magnetoresistance (TMR) reaching 270% and 0.4%, respectively. The temperature measurements indicate the exponentially decreasing dependence of TMR with increasing temperature, whereas TER is temperature independent. The electric ferromagnetic resonance measurements based on the spin‐diode effect shows the existence of two resonance peaks, from both ferromagentic electrodes, one identified as LSMO‐derived and characterized by low magnetization damping of α = 0.002 and the other from the Fe.
Multicomponent equimolar perovskite oxides (ME-POs) have recently emerged as a highly promising class of materials with unique synergistic effects, making them well-suited for applications in such areas as photovoltaics and micro- and nanoelectronics. High-entropy perovskite oxide thin film in the (Gd0.2Nd0.2La0.2Sm0.2Y0.2)CoO3 (RECO, where RE = Gd0.2Nd0.2La0.2Sm0.2Y0.2, C = Co, and O = O3) system was synthesized via pulsed laser deposition. The crystalline growth in an amorphous fused quartz substrate and single-phase composition of the synthesized film was confirmed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Surface conductivity and activation energy were determined using a novel technique implementing atomic force microscopy (AFM) in combination with current mapping. The optoelectronic properties of the deposited RECO thin film were characterized using UV/VIS spectroscopy. The energy gap and nature of optical transitions were calculated using the Inverse Logarithmic Derivative (ILD) and four-point resistance method, suggesting direct allowed transitions with altered dispersions. The narrow energy gap of RECO, along with its relatively high absorption properties in the visible spectrum, positions it as a promising candidate for further exploration in the domains of low-energy infrared optics and electrocatalysis.
In this study, electron diffraction patterns observed under high vacuum conditions for an SrTiO3 surface were interpreted in detail while paying special attention to the features of inelastic effects. The surface of the SrTiO2 was carefully prepared to enforce its termination with single domains of TiO2 layers at the top. The inelastic patterns were interpreted using analytical models. Two types of Kikuchi lines are recognized in this paper: those which can be described with the Bragg law and those which appear due to surface wave resonance effects. However, we also discuss that there exists a formal connection between the two types of the Kikuchi lines observed.
The process of preparation of nanostructured thin films in high vacuum can be monitored with the help of reflection high energy diffraction (RHEED). However, RHEED patterns, both observed or recorded, need to be interpreted. The simplest approaches are based on carrying out the Ewald construction for a set of rods perpendicular to the crystal surface. This article describes how the utilization of computer graphics may be useful for realistic reproduction of experimental conditions, and then for carrying out the Ewald construction in a reciprocal 3D space. The computer software was prepared in the Java programing language. The software can be used to interpret real diffractions patterns for relatively flat surfaces, and thus it may be helpful in broad research practice.
Changes in stoichiometry, temperature, strain and other parameters dramatically alter properties of LSMO perovskite. Thus, the sensitivity of LSMO may enable control of the magnetic properties of the film. This work demonstrates the capabilities of interface engineering to achieve the desired effects. Three methods of preparing STO substrates were conducted, i.e., using acid, buffer solution, and deionized water. The occurrence of terraces and their morphology depend on the preparation treatment. Terraces propagate on deposited layers and influence LSMO properties. The measurements show that anisotropy depends on the roughness of the substrate, the method of preparing the substrate, and oxygen treatment. The collected results suggest that the dipolar mechanism may be the source of LSMO anisotropy.