Highly efficient OLEDs are extremely demanded for the design of highly competitive energy-saving displays and lightings. In this article, we have systematically reviewed some most effective organic materials, eleven device architectural approaches, and outcoupling techniques to realize the high efficiency OLEDs.

Organic light emitting diodes (OLEDs) have been well known for their potential usage in the lighting and display industry. The device efficiency and lifetime have improved considerably in the last three decades. However, for commercial applications, operational lifetime still lies as one of the looming challenges. In this review paper, an in‐depth description of the various factors which affect OLED lifetime, and the related solutions is attempted to be consolidated. Notably, all the known intrinsic and extrinsic degradation phenomena and failure mechanisms, which include the presence of dark spot, high heat during device operation, substrate fracture, downgrading luminance, moisture attack, oxidation, corrosion, electron induced migrations, photochemical degradation, electrochemical degradation, electric breakdown, thermomechanical failures, thermal breakdown/degradation, and presence of impurities within the materials and evaporator chamber are reviewed. Light is also shed on the materials and device structures which are developed in order to obtain along with developed materials and device structures to obtain stable devices. It is believed that the theme of this report, summarizing the knowledge of mechanisms allied with OLED degradation, would be contributory in developing better‐quality OLED materials and, accordingly, longer lifespan devices.

Hole transporting layer plays a crucial role to realize high efficiency and long lifespan by balancing the charge carrier into the desired recombination zone.

Abundant molecules enable countless combinations of device architecture that might achieve the desirable high efficiency from organic light-emitting diodes (OLEDs). Due to the relatively high cost of OLED materials and facilities, simulation approaches have become a must in further advancing the field faster and saver. We have demonstrated here the use of state-of-art simulation approaches to investigate the effect of molecular orbital energy levels on the recombination of excitons in OLED devices. The devices studied are composed of 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) as hole transporting material (HTM), 4,4′-Bis(9-carbazolyl)-1,1′-biphenyl (CBP) as host, 2,2',2”-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) or bathophenanthroline (Bphen) as electron transporting materials. The outcomes reveal that exciton recombination highly sensitive to the energy-level alignment, injection barriers, and charge mobilities. A low energy-barrier (10⁶ times greater than that in the TPBi based device. The high carrier mobility of Bphen whose electron mobility is 5.2 × 10⁻⁴ cm² V⁻¹ s⁻¹ may lead to low charge accumulation and hence high exciton dynamics. The current study has successfully projected an in-depth analysis on the suitable energy-level alignments, which would further help to streamline future endeavours in developing efficient organic compounds and designing devices with superior performance.

We demonstrate a man-made lighting device of organic light-emitting diode (OLED) capable of yielding a sunlight-style illumination with various daylight chromaticities, whose color temperature ranges between 2300 and 8200 K, fully covering those of the entire daylight at different times and regions. The OLED employs a device architecture capable of simultaneously generating all the emissions required to form a series of daylight chromaticities. The wide color-temperature span may be attributed to that the recombination core therein can easily be shifted along the different emissive zones simply by varying the applied voltage via the use of a thin carrier-modulating layer.