Transition metal dichalcogenides (TMDs) with two dimensions (2D) exhibit remarkable electronic and optoelectronic properties that have made them a highly promising platform for the development of photodetectors (PDs).
Dye-sensitized solar cells (DSSCs) have attracted much attention as promising tools in renewable energy conversion technology. This is mainly because of their beneficial qualities, such as their impressive efficiency levels and low-cost fabrication techniques. An overview of MXene-modified electrodes in DSSCs is given in this review article. MXenes are two-dimensional (2D) transition metal carbides or nitrides with remarkable properties such as high conductivity and large surface area. MXenes’ properties make them an appealing material for various applications, including energy storage, catalysis, and electronic devices. MXene integration enhances ion transport, dye adsorption, and charge transport in DSSC electrodes. In-depth analysis of the use of 2D Mxene and integration with carbon nanotubes (CNTs), reduced graphene oxide (rGO), 2D MoS2, and hybrids like 2D–2D heterostructures for electrode modification in photovoltaics (PVs), including anodes, photoanodes, composite decorated electrodes, counter electrodes (CEs), and electrolytes, is provided in this review article. The effects on the performance metrics of various deposition techniques are discussed and assessed. The use of MXene-modified electrodes in DSSCs suggests potential for enhancing the performance and efficiency of these solar cells in general. The article examines this strategy's potential advantages and implications, illuminating the fascinating advancements in the area and emphasizing MXenes’ potential as a valuable substance for renewable energy applications. We also discuss the difficulties and potential benefits of using MXene-modified electrodes in DSSCs and emphasize the need for additional study to enhance stability, optimize MXene integration techniques, and enhance long-term device performance. The scalability and potential of MXene-based electrode modifications for commercial applications are also covered, addressing issues and prospects for the future, focusing on the necessity of more study. Electrodes modified with MXenes can improve DSSC performance and advance sustainable energy conversion.
21 August 2023 in Journal of Materials Chemistry C
A nanocomposite of CaO:MgAl2O4 was synthesized through a straightforward and cost-effective sol–gel method. The investigation of the novel CaO:MgAl2O4 nanocomposite encompassed an examination of its morphological and structural alterations, as well as an exploration of its photocatalytic activities and electrochemical characteristics. XRD analysis revealed a nanocomposite size of 24.15 nm. The band gap, determined through UV studies, was found to be 3.83 eV, and scanning electron microscopy (SEM) illustrated flake-like morphological changes in the CaO:MgAl2O4 samples. TEM, HRTEM, and SAED studies of a CaO:MgAl2O4 nanocomposite would reveal important details about its morphology, crystallography, and nanostructure. Photocatalytic activity was quantified by studying the degradation of Acid Red-88 (AR-88) dye in a deionized solution, achieving a 70% dye degradation under UV irradiation in 120 min. Plant growth examinations were carried out using dye degraded water to test its suitability for agriculture. The electrochemical energy storage and sensing applications of the prepared nanocomposite were examined using CaO:MgAl2O4 modified carbon paste electrode through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). In conclusion, the synthesized CaO:MgAl2O4 nanocomposite demonstrated promising morphological and structural characteristics, efficient photocatalytic activity, and potential applications in electrochemical energy storage, highlighting its versatility for various technological and environmental applications. Graphical abstract