Based on a critical analysis of literature data, new model concepts on the mechanism of microarc oxidation (MAO) are developed. The correctness of these model concepts is confirmed by experimental results on the average growth rate of oxide-ceramic coatings for different duration of the MAO process on AД31, MA2-1, and MЛ-5 alloys, the morphology of the surface structure of coatings of different thickness, the comparative electrical strength of dielectric coatings, which is assessed during self-quenching of the MAO process and in air. Equivalent electric circuits developed describe this process and are experimentally shown to be the “tool” which allows controlling MAO of aluminum and magnesium alloys.
The energy diagram of stationary magnetization states existing in polycrystalline cobalt nanoparticles in the range of diameters 20 ≤ D ≤ 60 nm has been calculated by means of numerical simulation. It is shown that in polycrystalline cobalt nanoparticles in the range of diameters D ≥ 32 nm only vortex states with low average magnetization are present, whereas mostly quasi-uniform states are realized in nanoparticles with diameter D ≤ 24 nm. Thus, the effective single-domain diameter of polycrystalline cobalt nanoparticles is estimated to be Dc = 24 nm. It is approximately two times smaller than the actual single-domain diameter of monocrystalline cobalt nanoparticle, Dc0 = 45 nm. The hysteresis loops of a dilute assembly of polycrystalline cobalt nanoparticles in the range of diameters D ≤ Dc are characterized by a coercive force that is approximately 2.5 times less compared with that of the randomly oriented assembly of monocrystalline cobalt nanoparticles.
6 July 2019 in International Journal of Minerals, Metallurgy and Materials
Fixation screws and other temporary magnesium alloy fixation devices are used in orthopedic practice because of their biodegradability, biocompatibility and acceptable biodegradation rates. The substitution of dissolving implant by tissues during the healing process is one of the main requirements for biodegradable implants. Previously, clinical tests showed the effectiveness of Ga ions on bone tissue regeneration. This work is the first systematic study on the corrosion rate and biocompatibility of Mg–Zn–Ga–(Y) alloys prepared by hot extrusion, where Ga is an additional major alloying element, efficient as a bone-resorption inhibitor. Most investigated alloys have a low corrosion rate in Hanks’ solution close to ~0.2 mm/year. No cytotoxic effects of Mg–2Zn–2Ga (wt.%) alloy on MG63 cells were observed. Thus, considering the high corrosion resistance and good biocompatibility, the Mg–2Zn–2Ga alloy is possible for applications in osteosynthesis implants with improved bone tissue regeneration ability.