Mixed (FAPbI3)₀.₉₂(MAPbBr3)₀.₀₈ perovskite thin films exhibit strong nonlinear optical responses, rendering them promising candidates for applications in photonics and optical communications. In this work, we present a systematic study on the ultrafast third-order nonlinear optical processes in mixed perovskite nanocrystals (NCs) by exploring the generation of third harmonic radiation and giant two-photon absorption-based photoluminescence (PL) when excited by femtosecond laser pulses of a 1030 nm central wavelength. A comparative analysis of the coherent third harmonic generation in the thin-film-containing perovskite nanocrystals has shown a 40× enhancement of the third harmonic signal compared to the signal generated in the pure quartz substrate. The cubic dependence of the third-nonlinear optical response of the (FAPbI₃)₀.₉₂(MAPbBr₃)₀.₀₈ perovskites on the intensity of the driving radiation was identified using broadband 38 femtosecond driving pulses. The positive nonlinear refractive index (γ = +1.4 × 10⁻¹² cm²·W⁻¹) is found to play an important role in improving the phase-matching conditions of the interacting pulses by generating a strong third order harmonic. The giant two-photon absorption (TPA)-assisted PL peak was monitored and a blue shift of the PL was obtained in the higher intensity range of the laser pulses, with the absorption coefficient β estimated to be~+7.0 cm·MW⁻¹ at a 1030 nm laser wavelength.

Application of high pulse repetition rate lasers opens the way for increasing the average flux of the high-order harmonics generating in the ions- and nanoparticles-containing plasmas ablated on the surfaces of various metal targets. We demonstrate the harmonic generation of 37 fs, 150 kHz, 1030 nm, 0.5 mJ pulses in different plasmas. The formation of plasma plumes on the surfaces of carbon, titanium, boron, zinc, and manganese targets was performed during laser ablation, using 250 fs pulses from the same laser. The ablation of the mixed powder of boron nanoparticles and silver microparticles was used for generation of harmonics with high yield. Harmonics up to the fortieth orders from the carbon plasma were obtained. The estimated conversion efficiencies in laser-produced plasmas were ≤10⁻⁵. The photon flux for a single harmonic generating in carbon plasma was estimated to be 8 × 10¹³ photons/s.

We demonstrate the formation of permanent and iridescent colors on aluminum, copper, steel, and brass surfaces using femtosecond laser-induced periodic and non-periodic nanostructuring. We show that both the permanent and iridescent colors of the metal surfaces can be erased and re-colored using a second stage of laser processing. A correlation was found between the spectral reflective properties of the laser-processed surfaces and their wettability properties. Transition from superhydrophilic to superhydrophobic response is observed while tailoring the optical reflectance of the metal surfaces. We employ a high power femtosecond fiber laser at 150 kHz repetition rate, which notably reduces the processing time, making this technique attractive for practical applications.