Composite polymer materials featured superior thermal conductivity, flame retardancy, and electromagnetic shielding performance are increasingly in demand due to the rapid development of highly miniaturized, portable, and flexible electronic devices. Herein, a facile and green ball milling shear method is utilized for generating MXene@Boron nitride (MXene@BN). The multi‐functional fillers (MXene@BN) are constructed and incorporated into polydimethylsiloxane (PDMS) to prepare a multifunctional composite (PDMS/MXene@BN) for achieving improved electromagnetic interference (EMI) shielding performance and thermal conductivity as well as flame retardancy simultaneously. When the PDMS/MXene@BN composite has a MXene@BN loading of 2.4 wt.%, it exhibits a high thermal conductivity of 0.59 W m ⁻¹ K ⁻¹ , which is 210% higher than that of the pure PDMS matrix. This is attributed to its unique chestnut‐like double‐layer structure. With a smoke production rate (SPR) of 0.04 m ² s ⁻¹ and total smoke production (TSP) of 3.51 m ² , PDMS/MXene@BN 2.4 composite exhibits superb smoke suppression properties. These SPR and TSP values are 63.20% and 63.50% lower than the corresponding values of pure PDMS. Moreover, the EMI SE of the PDMS/MXene@BN 2.4 can reach 26.3 dB at 8.5 GHz. The work reported herein provides valuable insight into developing composites with multiple functions, which show strong potential for application in advanced packaging materials.

As technology develops at a rapid pace, electromagnetic and radiation pollution have become significant issues. These forms of pollution can cause many important environmental issues. If they are not properly managed and addressed, they will be everywhere in the global biosphere, and they will have devastating impacts on human health. In addition to minimizing sources of electromagnetic radiation, the development of lightweight composite shielding materials to address interference from radiation has become an important area of research. A suitable shielding material can effectively reduce the harm caused by electromagnetic interference/radiation. However, membrane shielding materials with general functions cannot effectively exert their shielding performance in all fields, and membrane shielding materials used in different fields must have specific functions under their use conditions. The aim of this review was to provide a comprehensive review of these issues. Firstly, the causes of electromagnetic/radiation pollution were briefly introduced and comprehensively identified and analyzed. Secondly, the strategic solutions offered by membrane shielding materials to address electromagnetic/radiation problems were discussed. Then, the design concept, technical innovation, and related mechanisms of the existing membrane shielding materials were expounded, the treatment methods adopted by scholars to study the environment and performance change laws were introduced, and the main difficulties encountered in this area of research were summarized. Finally, on the basis of a comprehensive analysis of the protection provided by membrane shielding materials against electromagnetic/radiation pollution, the action mechanism of membrane shielding materials was expounded in detail, and the research progress, structural design and performance characterization techniques for these materials were summarized. In addition, the future challenges were prospected. This review will help universities, research institutes, as well as scientific and technological enterprises engaged in related fields to fully understand the design concept and research progress of electromagnetic/radiation-contaminated membrane shielding materials. In addition, it is hoped that this review will facilitate efforts to accelerate the research and development of membrane shielding materials and offer potential applications in areas such as electronics, nuclear medicine, agriculture, and other areas of industry.

Nanoscopic therapeutic systems that incorporate therapeutic agents, molecular targeting, and imaging capabilities have gained momentum and exhibited significant therapeutic potential. In this study, multifunctional polymeric nanoparticles with controlled drug delivery, cancer‐targeted capability, and efficient magnetic resonance imaging (MRI) contrast characteristics were formulated and applied in the treatment of castration‐resistant prostate cancer (CRPC). The “core‐shell” targeted nanoparticles (NPs) were synthesized by the self‐assembly of a prefunctionalized amphiphilic triblock copolymer composed of poly(lactic‐co‐glycolic‐acid) (PLGA), polyethylene glycol (PEG), and the Wy5a aptamer (Apt), which have been screened for targeting the CRPC cell line PC‐3 by cell‐SELEX technique as described in our previous study. Docetaxel (Dtxl) and a cluster of hydrophobic superparamagnetic iron oxide (SPIO) nanoparticles were simultaneously encapsulated into the targeted nanoparticles. The targeted NPs showed a controlled drug release and an increased contrast‐enhanced MRI capability. The presence of Wy5a on the nanoparticle surface resulted in the cancer‐targeted delivery to PC‐3 cells in vitro and in vivo. In vitro MRI and cytotoxicity studies demonstrated the ultrasensitive MRI and increased cytotoxicity of these targeted NPs. In vivo studies revealed that the targeted NPs exhibited a more efficacious antitumor capability without significant systemic toxicity. Our data suggested that these targeted NPs may be a promising drug delivery system for the efficacious treatment of CRPC.

The mechanical performance is critical for hydrogels that are used as strain sensors. p-Aramid nanofiber (ANF) is preferable as an additive to the reinforce the mechanical performance of a poly(vinyl alcohol) (PVA). However, due to the limited hydrogen bond sites, the preparation of ultra-stretchable, ANF-based hydrogel strain sensor is still a challenge. Herein, we reported an ultra-stretchable PVA hydrogel sensor based on tea stain-inspired ANFs. Due to the presence of numerous phenol groups in the tannic acid (TA) layer, the interaction between PVA and the ANFs was significantly enhanced even though the mass ratio of TA@ANF in the hydrogel was 2.8 wt‰. The tensile breaking modulus of the PVA/TA@ANF/Ag hydrogel sensor was increased from 86 kPa to 326 kPa, and the tensile breaking elongation was increased from 356% to 602%. Meanwhile, the hydrogel became much softer, and no obvious deterioration of the flexibility was observed after repeated use. Moreover, Ag NPs were formed in situ on the surfaces of the ANFs, which imparted the sensor with electrical conductivity. The hydrogel-based strain sensor could be used to detect the joint movements of a finger, an elbow, a wrist, and a knee, respectively. This ultra-stretchable hydrogel described herein was a promising candidate for detecting large-scale motions.