Impulsivity has been associated with several psychiatric disorders such as substance abuse. The Barratt Impulsiveness Scale (BIS-11) is one of the most commonly administered self-reports for the assessment of impulsiveness in both research and clinical settings. There is a version for adolescents called BIS-11-A, which has not been yet properly adapted to Spanish population. The goal of this study is to offer an alternative and more adequate Spanish version of the BIS-1-A, as well as to assess its psychometric properties including factor structure, reliability and predictive validity regarding substance use (last month alcohol, tobacco and cannabis use, presence of last month intoxication, binge drinking and problem drinking). The BIS-11-A and items from the European School Survey Project on Alcohol and other Drugs (ESPAD) were applied to1,183 students (aged 12-14) at 16 Spanish secondary schools. The BIS-11-A showed a bidimensional factor structure, high reliability (Cronbach's alpha = .87) and good capacity for identifying substance use, binge drinking and problem drinking (sensitivity = 67.3-75%; specificity = 83.4-85.4%). The BIS-11-A Spanish version is a reliable and valid instrument for be used among early adolescents.