Energy harvesting technology has recently gained attraction as it enables the utilization of diverse ambient energy sources. Reverse electrodialysis (RED) is such a technique that converts electrical energy from the concentration gradient between a concentrated solution (e.g., seawater) and a diluted solution (e.g., fresh water). We experimentally investigated a RED device using nanoporous polycarbonate track‐etch membranes. We performed the parametric study by varying the concentration differences, the pore size, and the electrolyte types. We characterized the RED performance in terms of maximum voltage, maximum current, and maximum power. The experimental results showed that the maximum voltage has a nonlinear dependency on the concentration difference with the highest value around the 100:1 concentration ratio. The maximum current and maximum power, on the other hand, monotonically increase as the concentration difference increases. We also found that the performance of the RED cell is enhanced with the decreased pore size in the experiments for the nominal diameter ranging from 15 to 100 nm. The results with different cations show that the electricity generation of the RED cell increases as the ion mobility increases or the valence number decreases. Copyright © 2013 John Wiley & Sons, Ltd.

Clean and sustainable energy generation from ambient environments is important not only for large scale systems, but also for tiny electrical devices, because of the limitations of batteries or external power sources. Chemical concentration gradients are promising energy resources to power micro/nanodevices sustainably without discharging any pollutants. In this paper, an efficient microplatform based on reverse electrodialysis, which enables high ionic flux through three dimensional nanochannel networks for high power energy generation, is demonstrated. Highly effective cation-selective nanochannel networks are realized between two microfluidic channels with geometrically controlled in situ self-assembled nanoparticles in a cost-effective and simple way. The nano-interstices between the assembled nanoparticles have a role as collective three-dimensional nanochannel networks and they allow higher ionic flux under concentration gradients without decreasing diffusion potential, compared to standard one-dimensional nanochannels. An in-depth experimental study with theoretical analysis shows that the electrical power of the presented system can be flexibly tuned or further optimized by changing the size, material, and shape of the assembled nanoparticles or by the geometric control of the microchannel. This microfluidic power generation system can be readily integrated with existing lab on a chip systems in the near future and can also be utilized to investigate nanoscale electrokinetics.

We propose a new type of micro/nano fluidic mixer based on non-equilibrium electrokinetics and demonstrate its mixing performance. We fabricate the device with two-step reactive ion etching, one for nanochannels and one for microchannels. Mixing is achieved by strong vortex structures formed near the micro/nano channel interface. We expect the proposed device to be beneficial in the development of micro total analysis systems, since it is simple in its design with minimal fabrication complications.

We report an active micromixer which utilizes vortex generation due to non-equilibrium electrokinetics near the interface between a microchannnel and a nanochannel networks membrane (NCNM), constructed from geometrically controlled in situ self-assembled nanoparticles. A large interfacing area where it is possible to generate vortices can be realized, because nano-interstices between the assembled nanoparticles are intrinsically collective three-dimensional nanochannel networks, which may be compared to typical silicon-based 2D nanochannels. The proposed mixer shows a 2-fold shorter mixing time (~0.78 ms) and a 34-fold shorter mixing length (~7.86 μm) compared to conventional 2D nanochannels.

This paper proposes a novel method to form ion-selective nanochannel networks between two microfluidic channels using geometrically controlled in situ self-assembled nanoparticles. We present a thorough experimental and theoretical analysis of nanoscale electrokinetics using the proposed microplatform. The nano-interstices between these assembled nanoparticles serve as the nanopores of ion-selective membranes with equivalent pore size. Its inherent characteristics (compared with the conventional one-dimensional nanochannels) are a high ionic flux and a low fluidic resistance because these nanopore clusters have a role as collective three-dimensional nanochannel networks, which result in a highly efficient performance beneficial for various applications. Another uniqueness of our system is that the electrical characteristics (such as ion transport through the nanochannel networks and the decrease in the limiting current region) can be tuned quantitatively or even optimized by changing the geometry of the microchannel and the pH condition of the working solution or by appropriately selecting the size and materials of the assembled nanoparticles. The correlation between these tuning parameters and nanoscale electrokinetics is deeply investigated with carefully designed experiments and their mechanism is thoroughly examined by a theoretical study. We expect that the presented system and methodology can contribute to opening new application fields, such as biomolecule separation/filtering/accumulation/analysis, bioelectronics, and energy generation.