Ricardo M. F. Fernandes

Dr. Ricardo M. F. Fernandes

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Research Focus & Metrics

Academic Career Length

17Years (2010-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 October 2015 in Langmuir
Verified
Journal Article
Closed access
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
BFBárbara Abreu Teixeira Brito e Faro
Bárbara Abreu Teixeira Brito e Faro
BCBárbara Claro
Bárbara Claro
MBMatat Buzaglo
Matat Buzaglo
Oren RegevOren Regev
Oren Regev
EMEduardo Marques
Eduardo Marques

1 August 2011 in Colloids and Surfaces B: Biointerfaces
Verified
Journal Article
Closed access
RBRodrigo O. Brito
Rodrigo O. Brito
Sandra SilvaSandra Silva
Sandra Silva
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
EMEduardo Marques
Eduardo Marques
JEJosé Enrique-Borges
José Enrique-Borges
Maria Luísa ValeMaria Luísa Vale
Maria Luísa Vale

1 September 2018 in Polymer
Verified
Journal Article
Closed access
RNRoey Nadiv
Roey Nadiv
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
GOGuy Ochbaum
Guy Ochbaum
JDJing Dai
Jing Dai
MBMatat Buzaglo
Matat Buzaglo
Oren RegevOren Regev
Oren Regev

1 July 2019 in Journal of Colloid and Interface Science
Verified
Journal Article
Closed access
BFBárbara Abreu Teixeira Brito e Faro
Bárbara Abreu Teixeira Brito e Faro
JRJessica Rocha
Jessica Rocha
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
Oren RegevOren Regev
Oren Regev
IFIstván Furó
István Furó
EMEduardo Marques
Eduardo Marques

15 November 2011 in European Journal of Organic Chemistry
Verified
Journal Article
Closed access
PDF file
Sandra SilvaSandra Silva
Sandra Silva
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
EMEduardo Marques
Eduardo Marques
Maria Luísa ValeMaria Luísa Vale
Maria Luísa Vale

24 September 2018 in The Journal of Physical Chemistry C
Verified
Journal Article
Open access
JDJing Dai
Jing Dai
RFRicardo M. F. Fernandes
Ricardo M. F. Fernandes
Oren RegevOren Regev
Oren Regev
EMEduardo Marques
Eduardo Marques
IFIstván Furó
István Furó
Debundling and dispersing single-walled carbon nanotubes (SWNTs) is essential for applications but the process is not well understood. In this work, aqueous SWNT dispersions were produced by sonicating pristine SWNT powder in the presence of an amphiphilic triblock copolymer (Pluronic F127) as dispersant. Upon centrifugation, one obtains a supernatant with suspended individual tubes and thin bundles and a precipitate with large bundles (and impurities). In the supernatant, that constitutes the final dispersion, we determined the dispersed SWNT concentration by thermogravimetric analysis (TGA) and UV-Vis spectroscopy and the dispersant concentration by 1H NMR. The fraction of dispersant adsorbed at the SWNT surface was obtained by 1H diffusion NMR. Sigmoidal dispersion curves recording the concentration of dispersed SWNTs as a function of supernatant dispersant concentration were obtained at different SWNT loadings and sonication times. As SWNT bundles are debundled into smaller and smaller ones, the essential role of the dispersant is to sufficiently quickly cover the freshly exposed surfaces created by shear forces induced during sonication. Primarily kinetic reasons are behind the need for dispersant concentrations required to reach a substantial SWNT concentration. Centrifugation sets the size-threshold below which SWNT particles are retained in the dispersion, and consequently determines the SWNT concentration as a function of sonication time.