In this paper, we focus on the synchronization between integer-order chaotic systems and a class of fractional-order chaotic system using the stability theory of fractional-order systems. A new sliding mode method is proposed to accomplish this end for different initial conditions and number of dimensions. More importantly, the vector controller is one-dimensional less than the system. Furthermore, three examples are presented to illustrate the effectiveness of the proposed scheme, which are the synchronization between a fractional-order Chen chaotic system and an integer-order T chaotic system, the synchronization between a fractional-order hyperchaotic system based on Chen’s system and an integer-order hyperchaotic system, and the synchronization between a fractional-order hyperchaotic system based on Chen’s system and an integer-order Lorenz chaotic system. Finally, numerical results are presented and are in agreement with theoretical analysis.