A novel polyvinyl alcohol (PVA)/calcium carbonate-based double-layer cationic dye adsorbent was developed. Polyvinyl alcohol (50 wt %) and calcium carbonate (50 wt %) were used together with borax as a cross-linking agent. The nanocomposite was prepared using only water, without the need for any toxic solvent or hazardous chemical. The final samples were obtained by the solvent casting method. The nanocomposite adsorbent was characterized using a Fourier transform infrared (FTIR) spectroscope and a scanning electron microscope (SEM). The adsorption performance on two cationic dyes, i.e., methylene blue and safranin was studied. Dye adsorption was quantified by measuring the nanocomposite swelling, contact time, and dye concentration. Pseudo first-order and pseudo second-order kinetic models as well as intraparticle diffusion model were used to model the adsorption kinetics. Moreover, the isotherm dye adsorption was investigated by Langmuir and Freundlich models. The results revealed that the developed nanocomposite has relatively high adsorption efficiency and short adsorption time and retains its performance after several successive absorption–desorption processes. The results also showed that the pseudo-second-order model best describes the adsorption kinetics, and the Freundlich isotherm model has a better compatibility with the experimental data. Finally, an adsorption mechanism was proposed for the dye removal process. The developed PVA/CaCO₃ nanocomposite can be potentially used for efficient dye removal in wastewater treatments.

Autoclaved aerated concrete (AAC) blocks have widespread popularity in the construction industry. In addition to lightness, these materials have other advantages, including fire resistance, low acoustic and thermal conductivity, ease of cutting and grooving, and simple transportation. Since the behavior of AAC under severe dynamic loading conditions such as blast loads has not been adequately studied in the literature, in the current paper, the behavior of masonry walls constructed with AAC blocks was evaluated under blast loading. In this study, after performing experimental testing on materials and obtaining their compressive, tensile, and shear strength values, the finite element (FE) models of AAC-based masonry walls were created in the ABAQUS/Explicit nonlinear platform. Three different wall thicknesses of 15, 20, and 25 cm were simulated, and the models were analyzed under a lateral explosion caused by 5 and 7 kg of TNT at the stand-off distances of 2, 5, and 10 m from the wall face. The stress distributions, displacement responses, adsorbed energy, and crack propagation pattern were investigated in each case. The results showed the inappropriate behavior of these materials against explosion loads, especially at shorter distances and on walls with less thickness. The outcome gives valuable information to prioritize these walls for possible blast strengthening.

In recent years, the mold-opening foam injection molding technology has received great attention as a breakthrough technology for the production of low density and open-cell foams of three-dimensional geometries. Despite the earlier studies, there has been little investigation on the control of the foaming temperature of this foam manufacturing process. To help understand the mechanisms behind this technology, this paper presents a numerical approach to simulate the cooling of the polymer/gas mixture inside the mold cavity, and thereby, estimating the foaming temperature of this manufacturing process. The temperature of the material inside the mold cavity prior to the mold-opening foam expansion process was mathematically modeled and resolved using finite difference approximation. Iteration considerations to the exothermic crystallization phenomenon for semi-crystalline polymers were also presented with reference to the non-isothermal crystallization characteristics from the differential scanning calorimetry (DSC) analysis. The numerically simulated results were shown to agree with the results obtained from a set of mold-opening foam injection molding experiments.