The low recovery of oil from tight liquid-rich formations is still a major challenge for a tight reservoir. Thus, supercritical CO2 flooding was proposed as an immense potential recovery method for production improvement. While up to date, there have been few studies to account for the formation properties’ variation during the CO2 Enhanced Oil Recovery (EOR) process, especially investigation at the micro-scale. This work conducted a series of measurements to evaluate the rock mechanical change, mineral alteration and the pore structure properties’ variation through the supercritical CO2 (Sc-CO2) injection process. Corresponding to the time variation (0 days, 10 days, 20 days, 30 days and 40 days), the rock mechanical properties were analyzed properly through the nano-indentation test, and the mineralogical alterations were quantified through X-ray diffraction (XRD). In addition, pore structures of the samples were measured through the low-temperature N2 adsorption tests. The results showed that, after Sc-CO2 injection, Young’s modulus of the samples decreases. The nitrogen adsorption results demonstrated that, after the CO2 injection, the mesopore volume of the sample would change as well as the specific Brunauer–Emmett–Teller (BET) surface area which could be aroused from the chemical reactions between the CO2 and some authigenic minerals. XRD analysis results also indicated that mesopore were altered due to the chemical reaction between the injected Sc-CO2 and the minerals.
Basalt is prevalent in the Earth’s crust and makes up about 90% of all volcanic rocks. The earth is warming at an alarming rate, and there is a search for a long-term solution to this problem. Geologic carbon storage in basalt offers an effective and durable solution for carbon dioxide sequestration. Basaltic rocks are widely used for road and building construction and insulation, soil amendment, and in carbon storage. There is a need to understand the parameters that affect this process in order to achieve efficient carbon mineralization. This review systematically analyzes peer-reviewed studies and project reports published over the past two decades to assess the mechanisms, effectiveness, and challenges of carbon mineralization in basaltic formations. Key factors such as mineral composition, pH, temperature and pressure are evaluated for their impact on mineral dissolution and carbonate precipitation kinetics. The presence of olivine and basaltic glass also accelerates cation release and carbonation rates. The review includes case studies from major field projects (e.g., CarbFix and Wallula) and laboratory experiments to illustrate how mineralization performs in different geological environments. It is essential to maximize mineralization kinetics while ensuring the formation of stable carbonate phases in order to achieve efficient and permanent carbon dioxide storage in basaltic rock.
4 November 2013 in Frontiers of Environmental Science & Engineering
The petroleum reservoir represents a complex heterogeneous system that requires thorough characterization prior to the implementation of any incremental recovery technique. One of the most commonly utilized and successful secondary recovery techniques is waterflooding. However, a lack of sufficient investigation into the inherent behavior and characteristics of the reservoir formation in situ can result in failure or suboptimal performance of waterflood operations. Therefore, a comprehensive understanding of the geological history, static and dynamic reservoir characteristics, and petrophysical data is essential for analyzing the mechanisms and causes of waterflood inefficiency and failure. In this study, waterflood inefficiency was observed in the Morrow B reservoir located in the Farnsworth Unit, situated in the northwestern shelf of the Anadarko Basin, Texas. To assess the potential mechanisms behind the inefficiency of waterflooding in the east half, geological, petrophysical, and reservoir engineering data, along with historical information, were integrated, reviewed, and analyzed. The integration and analysis of these datasets revealed that several factors contributed to the waterflood inefficiency. Firstly, the presence of abundant dispersed authigenic clays within the reservoir, worsened by low reservoir quality and high heterogeneity, led to unfavorable conditions for waterflood operations. The use of freshwater for flooding exacerbated the adverse effects of sensitive and migratory clays, further hampering the effectiveness of the waterflood. In addition to these factors, several reservoir engineering issues played a significant role in the inefficiency of waterflooding. These issues included inadequate perforation strategies due to the absence of detailed hydraulic flow units (HFUs) and rock typing, random placement of injectors, and uncontrolled injected fresh water. These external controlling parameters further contributed to the overall inefficiencies observed during waterflood operations in the east half of the reservoir. A detailed understanding of the mechanistic factors of inefficient waterflood operation will provide adequate insights into the development of the improved recovery technique for the field.
This paper synthesizes lessons learned from drilling a CO2-storage stratigraphic well in the San Juan Basin (New Mexico, USA) to clarify drivers of operational incidents and to inform future well planning. A literature review of regional drilling problems was combined with pre-drill engineering based on offset-well history and a geomechanical model, including casing, cementing, and hydraulics designs developed in commercial software; these designs were compared with field execution to extract incident-specific lessons. The most frequent problems observed are lost circulation, stuck pipe, and poor control of drilling parameters, consistent with complex lithology and reservoir pressure depletion that reduces fracture pressure below anticipated values. Based on the lessons learned, three mitigations are proposed as follows: (1) update the geomechanical model with the latest pore, fracture pressure estimates; (2) apply underbalanced drilling using nitrified mud by injecting nitrogen through a parasite string while drilling intermediate and production sections; and (3) maintain operating limits (weight on bit < 44.5 kN, top-drive rotation < 45 rpm, and pump rate < 1.32 m3/min) to improve fluid returns through low-fracture-pressure intervals. Simulation results support the applicability of the proposed solutions.
Basalt is a promising geological medium for CO₂ storage because of its potential for permanent mineral trapping, although fluid–rock reactions can alter pore structure and hydraulic properties. This study investigates coupled axial deformation, hydraulic and geochemical evolution of basalt during CO₂-saturated brine flow at 88 °C and approximately 210 bar pore pressure. In situ axial deformation, differential pressure and apparent permeability were monitored continuously, while effluent chemistry, mineral saturation states and pore-structure properties were evaluated. Six axial deformation stages were identified, with a pronounced hydraulic transition after approximately 115 pore volumes (PV) injected. Larger deformation magnitudes coincided with decreasing differential pressure and increasing apparent permeability, and absolute axial strain change was positively correlated with stage-averaged apparent permeability (r = 0.919, R² = 0.8437). Absolute permeability increased from 2.41 to 8.55 mD, while measured porosity increased only slightly from 9.15% to 9.51%. Fe and SiO₂ concentrations generally increased during reactive flow, and late-stage saturation indices indicated thermodynamic favorability for selected secondary phases. Nitrogen adsorption measurements showed changes in accessible pore structure. These results demonstrate concurrent deformation, hydraulic and geochemical evolution and indicate that permeability evolution cannot be explained by changes in bulk porosity alone.