Currently, photocatalytic reactions under solar illumination have attracted worldwide attention due to the tremendous set of associated environmental problems. Taking sunlight into account, it is indispensable to develop highly effective photocatalysts. Strontium titanate, SrTiO₃ (STO), is a cubic perovskite-type semiconductor, an inexpensive material with high thermal stability and corrosion resistance that exhibits a similar energy bandgap to TiO₂ and can represent an interesting alternative in photocatalytic applications. Particle size can significantly affect both photocatalytic and photoelectrochemical properties of a photocatalyst, thus altering the photooxidation of organic pollutants in air or water. In this context, this research aims at investigating the photocatalytic features of nano- and micro-sized commercial STO powders towards the photodegradation of diclofenac (DFC), a non-steroidal, anti-inflammatory drug, widely used as analgesic, antiarthritic, and antirheumatic. Both nano- and micro-STO photocatalysts exhibited remarkable photocatalytic efficiency towards DCF, reaching photodegradation efficiency higher than 90% within one hour. Results obtained in simulated drinking water were also compared to those obtained in ultrapure water. Both STOs showed good stability during recycling tests, maintaining high performances after three cycles. Eventually, active species were identified using various scavengers by trapping holes and radicals generated during the photocatalytic degradation process.

The major drawback of oxide-based sensors is the lack of selectivity. In this context, Sn_xTi_1−xO₂/graphene oxide (GO)-based materials were synthesized via a simple hydrothermal route, varying the titanium content in the tin dioxide matrix. Then, toluene and acetone gas sensing performances of the as-prepared sensors were systematically investigated. Specifically, by using 32:1 SnO₂/GO and 32:1 TiO₂/GO, a greater selectivity towards acetone analyte, also at room temperature, was obtained even at ppb level. However, solid solutions possessing a higher content of tin relative to titanium (as 32:1 Sn_0.55Ti_0.45O₂/GO) exhibited higher selectivity towards bigger and non-polar molecules (such as toluene) at 350 °C, rather than acetone. A deep experimental investigation of structural (XRPD and Raman), morphological (SEM, TEM, BET surface area and pores volume) and surface (XPS analyses) properties allowed us to give a feasible explanation of the different selectivity. Moreover, by exploiting the UV light, the lowest operating temperature to obtain a significant and reliable signal was 250 °C, keeping the greater selectivity to the toluene analyte. Hence, the feasibility of tuning the chemical selectivity by engineering the relative amount of SnO₂ and TiO₂ is a promising feature that may guide the future development of miniaturized chemoresistors.

A discrete π-hole···σ-hole dimer is synthesized and X-ray characterized. It presents a perfect thumbtack geometry where the σ-hole of the linear [AuI₂]^- anion points to the π-hole located above the central Au-atom of the [AuI₄]^- anion. Such discrete π-hole···σ-hole dimers are unprecedented in literature, since all mixed-valence gold(I/III) iodide compounds reported to date form infinite ···([AuI₄]^-···[AuI₂]^-) _n ·· chains in the solid state. If an excess of iodine is used for the synthesis, triiodide [I₃]^- ions are partially incorporated into the [AuI₂]^- sites, forming infinite chains. The nature of the anion···anion interaction has been studied considering two possibilities: (i) a π-hole coinage bond or (ii) σ-hole halogen bond using high-level density functional theory calculations, the quantum theory of atoms in molecules, and the noncovalent interaction plot index.