The formation of gas-filled bubbles on the surface of van der Waals crystals provides an ideal platform whereby the interplay of the elastic parameters and interlayer forces can be suitably investigated. Here, we combine experimental and numerical efforts to study the morphology of the bubbles at equilibrium and highlight unexpected behaviors that contrast with the common assumptions. We exploit such observations to develop an accurate analytical model to describe the shape and strain of the bubbles and exploit it to measure the adhesion energy between a variety of van der Waals crystals, showing sizable material-dependent trends.
Two-dimensional materials (2Dm) offer a unique insight into the world of quantum mechanics including van der Waals (vdWs) interactions, exciton dynamics and various other nanoscale phenomena. 2Dm are a growing family consisting of graphene, hexagonal-Boron Nitride (h-BN), transition metal dichalcogenides (TMDs), monochalcogenides (MNs), black phosphorus (BP), MXenes and 2D organic crystals such as small molecules (e.g., pentacene, C8 BTBT, perylene derivatives, etc.) and polymers (e.g., COF and MOF, etc.). They exhibit unique mechanical, electrical, optical and optoelectronic properties that are highly enhanced as the surface to volume ratio increases, resulting from the transition of bulk to the few- to mono- layer limit. Such unique attributes include the manifestation of highly tuneable bandgap semiconductors, reduced dielectric screening, highly enhanced many body interactions, the ability to withstand high strains, ferromagnetism, piezoelectric and flexoelectric effects. Using 2Dm for mechanical resonators has become a promising field in nanoelectromechanical systems (NEMS) for applications involving sensors and condensed matter physics investigations. 2Dm NEMS resonators react with their environment, exhibit highly nonlinear behaviour from tension induced stiffening effects and couple different physics domains. The small size and high stiffness of these devices possess the potential of highly enhanced force sensitivities for measuring a wide variety of un-investigated physical forces. This review highlights current research in 2Dm NEMS resonators from fundamental physics and an applications standpoint, as well as presenting future possibilities using these devices.
Flexible acoustic sensors with high sensitivity, excellent mechanical strength, and easy integration are urgently needed for wearable electronics. MXene holds great promise as a sensing material for this application. However, low flexibility and stability limit the performance of MXene‐based composites. To alleviate the aforementioned issue, a flexible pressure sensor based on MXene/poly(3,4‐ethylenediox‐ythiophene)‐poly(styrenesulfonate) (PEDOT:PSS) is fabricated and used as an acoustic sensor inhibiting high sensitivity, fast response time (57 ms), ultra‐thin thickness (30 μm), and remarkable stability. Excellent performance enables the sensor to detect and identify weak muscle movements and skin vibrations, such as word pronunciation and carotid artery pulse. Furthermore, by combining the proposed deep learning model based on number recognition convolutional neural network (NR‐CNN), speech recognition toward different pronunciations of numbers that appear frequently in daily conversations can be realized. High recognition accuracy (91%) is achieved by training and testing the proposed NR‐CNN with large amounts of data recorded by the sensor. Results demonstrate that the flexible and wearable MXene/PEDOT:PSS acoustic sensor accelerates intelligent artificial acoustics and possesses great potential for applications involving speech recognition and health monitoring.
30 August 2019 in Journal of Intelligent Material Systems and Structures
The noise and vibration effects of rails can have a significant impact on the environment surrounding the railways. Rail dampers are elements that are attached to the sides of the rail and can improve the track decay rate of rail and then enhance the rails’ ability to attenuate noises and vibrations. However, in practical applications, the most efficient rail damper design still cannot adjust its own parameters to adapt to different requirements because their stiffness and damping are fixed after designed. In this work, a tunable magnetorheological elastomer rail damper that works on the principle of a dynamic vibration absorber has been designed, analysed, characterised, and experimentally tested for the suppression of railway noise and vibration. The new rail damper incorporates variable stiffness magnetorheological elastomer layers, whose stiffness can be controlled by an externally applied magnetic field, to realise adaptive characteristics. Experimental characterisations of the magnetorheological elastomer rail damper were performed with an electromagnetic shaker. Subsequently, theoretical predictions of the track decay rate of a UIC-60 rail with different rail dampers and without rail damper were conducted; simulation results verified that magnetorheological elastomer rail dampers can improve the track decay rate of rail over a wider frequency range compared to conventional rail dampers and thus the performance of the magnetorheological elastomer rail damper outperforms other conventional rail dampers on rail noise reduction.
Since its fundamental inception from soap bubbles, Plateau’s law has sparked extensive research in equilibrated states. However, most studies primarily relied on liquids, foams or cellular structures, whereas its applicability has yet to be explored in nano-scale solid films. Here, we observed a variant Plateau’s law in networks of atomically thin domes made of solid two-dimensional (2D) transition metal dichalcogenides (TMDs). Discrete layer-dependent van der Waals (vdWs) interaction energies were experimentally and theoretically obtained for domes protruding in different TMD layers. Significant surface tension differences from layer-dependent vdWs interaction energies manifest in a variant of this fundamental law. The equivalent surface tension ranges from 2.4 to 3.6 N/m, around two orders of magnitude greater than conventional liquid films, enabling domes to sustain high gas pressure and exist in a fundamentally variant nature for several years. Our findings pave the way towards exploring variant discretised states with applications in opto-electro-mechanical devices.