CdSe-reduced graphene oxide (CdSe/RGO) composites were synthesized by a hydrothermal method. CdSe/RGO composites with different mass ratios were prepared. The structure and morphology of CdSe/RGO composites were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The synthesis of CdSe/RGO complexes was successfully demonstrated by Fourier infrared (FT-IR) and Raman spectra. CdSe nanoparticles in the CdSe/RGO composite were uniformly dispersed on the graphene surface. The study found that oxygen-containing functional groups such as hydroxyl (-OH) and carboxyl (-COOH) groups in graphene played a decisive role in the dispersion of CdSe. The third-order nonlinear optical properties of CdSe/RGO composites were measured by a single beam Z-scan technique. The experimental results showed that composites exhibited two-photon absorption and self-focusing nonlinear refraction properties. Additionally, the third-order nonlinear susceptibility of the composite material was obviously enhanced, which was mainly due to the good dispersion of CdSe nanoparticles on graphene.

Spiral phase plate (SPP) is the widely used method in the generation of vortex beam (VB) with fixed topological charges (TCs) for specific wavelength. Although VB with large TCs can be directly generated by using the SPP with high vortex order. The fabrication of high-quality SPPs with high vortex orders usually requires complex manufacturing process and high machining accuracy. An alternative method to generate VBs with large TCs is cascaded multiple SPPs with low order. In this study, we numerically calculate the transmitted light field of cascaded multiple SPPs according to the Huygens–Fresnel diffraction integral, and perform the experimental verifications. Based on cascading 6 SPPs (3 SPPs with TCs of 2, and 3 SPPs with TCs 4, respectively), an VB with TCs as high as 18 is generated. Furthermore, The TCs of the generated VB are detected by coaxial and off-axis interfering with fundamental Gaussian beam or its conjugate beam, respectively. The generated fork and spiral patterns allow us to distinguish the value and sign of TCs carried by the VB. The experimental results coincide well with the theoretical simulations. The fork pattern shows better resolution than the spiral one, and the petal pattern with small spiral allows us to distinguish large TCs with a higher resolution.

We have experimentally created perfect vortex beams (PVBs) by Fourier transformation of Bessel–Gaussian vortex beams, which are generated by modulating the fundamental Gaussian beam with the spiral phase plates and the axicons, respectively. Although the method has been used many times by other authors, as far as we know, few people pay attention to the quantitative relationship between the control parameters of the PVB and ring width. The effects of the waist radius of the fundamental Gaussian beam w_g, base angle of the axicon γ, and focal length of the lens f on the spot parameters (ring radius ρ, and ring half-width Δ) of PVB are systematically studied. The beam pattern of the generated Bessel–Gaussian beam for different propagation distances behind the axicon and the fundamental Gaussian beam w_g is presented. We showed experimentally that the ring radius ρ increases linearly with the increase of the base angle γ and focal length f, while the ring half-width Δ decreases with the increase of the fundamental beam waist radius w_g, and increases with enlarging the focal length f. We confirmed the topological charge (TC) of the PVB by the interferogram between the PVB and the reference fundamental Gaussian beam. We also studied experimentally that the size of the generated PVB in the Fourier plane is independent of the TCs. Our approach to generate the PVB has the advantages of high-power tolerance and high efficiency.

Spiral pattern is formed for coaxial interference between two vortex beams with different radii of wavefront curvatures and different topological charges (TCs). A theoretical model considering various parameters (such as phase difference, radius of wavefront curvature, and TCs) is established to predict all kinds of interference patterns. An improved Mach-Zehnder interferometer is set up in an experiment to generate different kinds of spiral patterns and verify the theoretical model. The number of spiral lobes is determined by the absolute value of TCs’ difference between two vortex beams, and the twist direction relates to the sign of TCs’ difference and the difference of reciprocals for the radii of wavefront curvature, clockwise for the same sign, and counterclockwise for the opposite signs. The twist direction of the spiral pattern reverses and the lobes direction near the core of the pattern changes obviously when the spherical wave changes from convergence to divergence.

Graphene-γMnS were prepared by facile one-step hydrothermal method. Structures and properties of samples were explored by characterization, and nonlinear optical (NLO) enhancement of nanocomposites (NCs) was fully studied. Nanoparticles and NCs were tested at 532 nm by a Z-scan technique. With γMnS attached in G layers, NLO susceptibility of graphene-γMnS was greatly improved under single-pulse laser irradiation compared with G and γMnS. The nonlinearity enhanced was attributed to local field effect and charge transfer between γMnS and graphene layers. And NLO property enhancement was restricted by non-radiative defects in graphene-γMnS. Exploring the mechanism of nonlinearity enhancement was significant for fabrication of NLO devices. However, the optical nonlinearity decreased first and then increased with further increased addition of GO, because the dispersion of γMnS attached on graphene surface might make density of sp² fragment and defects changed. Graphene-γMnS exhibited excellent and tunable NLO performance, illustrating that NCs materials have potential applications in NLO devices.