With the technological development of exploitation and separation, the primary source of lithium has gradually changed from ore to brine, which has become the main raw material, accounting for more than 80% of the total production. Resources of lithium-bearing brine are abundant in China. This paper has summarized the spatial and temporal distribution, characteristics, and formation mechanism of the lithium-rich brine in China, aiming to provide a comprehensive set of guidelines for future lithium exploitation from brines. Lithium brines usually exist in modern saline lakes and deep underground sedimentary rocks as subsurface brines. The metallogenic epoch of China's lithium-rich brine spans from the Triassic to the Quaternary, and these brines exhibit obvious regional distribution characteristics. Modern lithium-rich saline lakes are predominately located in the Qinghai-Tibet Plateau. In comparison, the subsurface lithium-rich brines are mainly distributed in the sedimentary basins of Sichuan, Hubei, Jiangxi, and the western part of the Qaidam Basin. Lithium-rich saline lakes are chloride-enriched, sulfate-enriched, and carbonate-enriched, while the deep lithium-rich brines are mainly chloride-enriched. On the whole, the value of Mg/Li in deep brine is generally lower than that of brine in saline lakes. The genesis of lithium-rich brines in China is not uniform, generally there are two processes, which are respectively suitable for salt lakes and deep brine.

Evaporites are widely distributed within continental “red beds” in the Lanping–Simao Basin, west Yunnan, China. Sr (Strontium), S (Sulfur), and O (Oxygen) isotope compositions have been measured on 54 sulfate or/and sulfate-bearing samples collected from Lanping, Nuodeng, Jinggu, Mengyejing, Baozang throughout the Lanping–Simao Basin. The ⁸⁷Sr/⁸⁶Sr ratios of all samples (0.708081 to 0.710049) are higher than those of contemporaneous seawater, indicating a significant continental contribution to the drainage basin. Sulfates in the Lanping Basin have higher ⁸⁷Sr/⁸⁶Sr ratios (0.709406 to 0.710049) than those (0.708081 to 0.709548) in the Simao Basin. Nevertheless, the δ³⁴S values of gypsums (13.4‰ to 17.6‰) in Lanping and Baozang fall within the range of Cretaceous seawater. Gypsums from a single section in Baozang have trends of decreasing δ³⁴S values and increasing ⁸⁷Sr/⁸⁶Sr ratios from base to top, indicating continental input played an increasingly significant role with the evaporation of brines. High δ³⁴S values (20.5‰ to 20.7‰) of celestites in Lanping are probably caused by bacterial sulfate reduction (BSR) process in which ³⁴S were enriched in residual sulfates and/or recycling of Triassic evaporites. The reduced δ³⁴S values of gypsums (9.5‰ to 10.4‰) in Nuodeng could have been caused by oxidation of sulfides weathered from Jinding Pb-Zn deposit. The complex O isotope compositions indicate that sulfates in the Lanping–Simao Basin had undergone sulfate reduction, re-oxidation, reservoir effects, etc. In conclusion, the formation of continental evaporites was likely derived from seawater due to marine transgression during the Cretaceous period. Meanwhile, non-marine inflows have contributed to the basin significantly.