The Earth’s surface comprises minerals diagnostic of weathering, deposition and erosion. The first continental-scale mineral maps generated from an imaging satellite with spectral bands designed to measure clays, quartz and other minerals were released in 2012 for Australia. Here we show how these satellite mineral maps improve our understanding of weathering, erosional and depositional processes in the context of changing weather, climate and tectonics. The clay composition map shows how kaolinite has developed over tectonically stable continental crust in response to deep weathering during northwardly migrating tropical conditions from 45 to 10 Ma. The same clay composition map, in combination with one sensitive to water content, enables the discrimination of illite from montmorillonite clays that typically develop in large depositional environments over thin (sinking) continental crust such as the Lake Eyre Basin. Cutting across these clay patterns are sandy deserts that developed <10 Ma and are well mapped using another satellite product sensitive to the particle size of silicate minerals. This product can also be used to measure temporal gains/losses of surface clay caused by periodic wind erosion (dust) and rainfall inundation (flood) events. The accuracy and information content of these satellite mineral maps are validated using published data.
In this study we tested the feasibility of the thermal infrared (TIR) wavelength region (within the atmospheric window between 8 and 11.5 μm) together with the traditional solar reflective wavelengths for quantifying soil properties for coarse-textured soils from the Australian wheat belt region. These soils have very narrow ranges of texture and organic carbon contents. Soil surface spectral signatures were acquired in the laboratory, using a directional emissivity spectrometer (μFTIR) in the TIR, as well as a bidirectional reflectance spectrometer (ASD FieldSpec) for the solar reflective wavelengths (0.4–2.5 μm). Soil properties were predicted using multivariate analysis techniques (partial least square regression). The spectra were resampled to operational imaging spectroscopy sensor characteristics (HyMAP and TASI-600). To assess the relevance of specific wavelength regions in the prediction, the drivers of the PLS models were interpreted with respect to the spectral characteristics of the soils’ chemical and physical composition. The study revealed the potential of the TIR (for clay: R2 = 0.93, RMSEP = 0.66% and for sand: R2 = 0.93, RMSEP = 0.82%) and its combination with the solar reflective region (for organic carbon: R2 = 0.95, RMSEP = 0.04%) for retrieving soil properties in typical soils of semi-arid regions. The models’ drivers confirmed the opto-physical base of most of the soils’ constituents (clay minerals, silicates, iron oxides), and emphasizes the TIR’s advantage for soils with compositions dominated by quartz and kaolinite.
Satellite-based hyperspectral imaging became a reality in November 2000 with the successful launch and operation of the Hyperion system on board the EO-1 platform. Hyperion is a pushbroom imager with 220 spectral bands in the 400-2500 nm wavelength range, a 30 meter pixel size and a 7.5 km swath. Pre-launch characterization of Hyperion measured low signal to noise (SNR<40:1) for the geologically significant shortwave infrared (SWIR) wavelength region (2000- 2500 nm). The impact of this low SNR on Hyperion's capacity to resolve spectral detail was evaluated for the Mount Fitton test site in South Australia, which comprises a diverse range of minerals with narrow, diagnostic absorption bands in the SWIR. Following radiative transfer correction of the Hyperion radiance at sensor data to surface radiance (apparent reflectance), diagnostic spectral signatures were clearly apparent, including: green vegetation; talc; dolomite; chlorite; white mica and possibly tremolite. Even though the derived surface composition maps generated from these image endmembers were noisy (both random and column), they were nonetheless spatially coherent and correlated well with the known geology. In addition, the Hyperion data were used to measure and map spectral shifts of <10 nm in the SWIR related to white mica chemical variations.
Remote sensing systems are largely used in geology for regional mapping of mineralogy and lithology mainly from airborne or spaceborne platforms. Earth observers such as Landsat, ASTER or SPOT are equipped with multispectral sensors, but suffer from relatively poor spectral resolution. By comparison, the existing airborne and spaceborne hyperspectral systems are capable of acquiring imagery from relatively narrow spectral bands, beneficial for detailed analysis of geological remote sensing data. However, for vertical exposures, those platforms are inadequate options since their poor spatial resolutions (metres to tens of metres) and NADIR viewing perspective are unsuitable for detailed field studies. Here, we have demonstrated that field-based approaches that incorporate thermal infrared hyperspectral technology with about a 40-nm bandwidth spectral resolution and tens of centimetres of spatial resolution allow for efficient mapping of the mineralogy and lithology of vertical cliff sections. We used the Telops lightweight and compact passive thermal infrared hyperspectral research instrument for field measurements in the Jura Cement carbonate quarry, Switzerland. The obtained hyperspectral data were analysed using temperature emissivity separation algorithms to isolate the different contributions of self-emission and reflection associated with different carbonate minerals. The mineralogical maps derived from measurements were found to be consistent with the expected carbonate results of the quarry mineralogy. Our proposed approach highlights the benefits of this type of field-based lightweight hyperspectral instruments for routine field applications such as in mining, engineering, forestry or archaeology.
1 February 2011 in Geochemistry: Exploration, Environment, Analysis