In this study, the dependence on the morphology and mechanical properties was analyzed when different amounts of polylactic acid are added to the polyethylene terephthalate polymer matrix using single-screw extrusion. Thermograms of the polymer blends obtained by differential scanning calorimetry couple to thermal gravimetric analysis show a displacement in the glass transition temperature with the amount of polylactic acid (1, 2.5, 5, and 7.5 wt%) added to the polymer matrix. Scanning electron microscopy and atomic force microscopy images showed two different kinds of morphology, both characteristics of miscible and partially miscible polymer blends. Fourier transform infrared spectroscopy measurements confirmed a physical interaction by hydrogen bond in the polymer blends. The impact resistance and tensile strength are reduced with the polylactic acid addition and are influenced by the fraction of segments of hydrogen bonded in the polyethylene terephthalate/polylactic acid blends as well as their miscibility. GRAPHICAL ABSTRACT

Thick and homogeneous hybrid film systems based on poly(methyl methacrylate) (PMMA) and CeO₂ nanoparticles were synthesized using the melt compounding method to improve thermal stability, mechanical and UV-shielding properties, as well as to propose them for use in the multifunctional materials industry. The effect of the inorganic phase on these properties was assessed by using two different weight percentages of synthesized CeO₂ nanoparticles (0.5 and 1.0 wt %) with the sol–gel method and thermal treatment at different temperatures (120, 235, 400, 600 and 800 °C). Thereafter, the nanoceria powders were added to the polymer matrix by single screw extrusion. The absorption in the UV region was increased with the crystallite size of the CeO₂ nanoparticles and the PMMA/CeO₂ weight ratio. Due to the crystallinity of CeO₂ nanoparticles, the thermal, mechanical and UV-shielding properties of the PMMA matrix were improved. The presence of CeO₂ nanostructures exerts an influence on the mobility of PMMA chain segments, leading to a different glass transition temperature.

In this work, the optimal conditions of synthesizing and purifying carbon nanotubes (CNTs) from ferrocene were selected at the first stage, where decomposition time, argon fluxes, precursor amounts, decomposition temperature (at 1023 K and 1123 K), and purification process (HNO₃ + H₂SO₄ or HCl + H₂O₂), were modulated through chemical vapor deposition (CVD) and compared to commercial CNTs. The processing temperature at 1123 K and the treatment with HCl + H₂O₂ were key parameters influencing the purity, crystallinity, stability, and optical/electrical properties of bamboo-like morphology CNTs. Selected multiwalled CNTs (MWCNTs), from 1 to 20 wt%, were electropolymerized through in-situ polarization with conductive polymers (CPs), poly(aniline) (PANI) and poly(pyrrole) (PPy), for obtaining composites. In terms of structural stability and electrical properties, MWCNTs obtained by CVD were found to be better than commercial ones for producing CPs composites. The CNTs addition in both polymeric matrixes was of 6.5 wt%. In both systems, crystallinity degree, related to the alignment of PC chains on MWCNTs surface, was improved. Electrical conductivity, in terms of the carrier density and mobility, was adequately enhanced with CVD CNTs, which were even better than the evaluated commercial CNTs. The findings of this study demonstrate that synergistic effects among the hydrogen bonds, stability, and conductivity are better in PANI/MWCNTs than in PPy/MWCNTs composites, which open a promissory route to prepare materials for different technological applications.

A viable alternative for the next generation of wound dressings is the preparation of electrospun fibers from biodegradable polymers in combination with inorganic nanoparticles. A poly(vinyl alcohol)-chitosan-silver nanoparticles (PVA-CTS-Ag NPs) system has been developed for antimicrobial and wound healing applications. Here, the preparation of PVA-CTS-Ag electrospun fibers using a two-step process is reported in order to analyze changes in the microstructural, mechanical, and antibacterial properties and confirm their potential application in the biomedical field. The Ag nanoparticles were well-dispersed into the chitosan matrix and their cubic structure after the electrospinning process was also retained. The Ag NPs displayed an average diameter of ~33 nm into the CTS matrix, while the size increased up to 213 nm in the PVA-CTS-Ag(NPs) fibers. It was observed that strong chemical interactions exist between organic (CTS) and inorganic phases through nitrogenous groups and the oxygen of the glycosidic bonds. A defect-free morphology was obtained in the PVA-CTS-Ag NPs final fibers with an important enhancement of the mechanical properties as well as of the antibacterial activity compared with pure PVA-CTS electrospun fibers. The results of antibacterial activity against E. coli and S. aureus confirmed that PVA-CTS-Ag(NPs) fibers can be potentially used as a material for biomedical applications.