TiO₂ exists naturally in three crystalline forms: Anatase, rutile, brookite, and TiO₂ (B). These polymorphs exhibit different properties and consequently different photocatalytic performances. This paper aims to clarify the differences between titanium dioxide polymorphs, and the differences in homophase, biphase, and triphase properties in various photocatalytic applications. However, homophase TiO₂ has various disadvantages such as high recombination rates and low adsorption capacity. Meanwhile, TiO₂ heterophase can effectively stimulate electron transfer from one phase to another causing superior photocatalytic performance. Various studies have reported the biphase of polymorph TiO₂ such as anatase/rutile, anatase/brookite, rutile/brookite, and anatase/TiO₂ (B). In addition, this paper also presents the triphase of the TiO₂ polymorph. This review is mainly focused on information regarding the heterophase of the TiO₂ polymorph, fabrication of heterophase synthesis, and its application as a photocatalyst.

Titanium dioxide (TiO₂) has been widely applied as a photocatalyst for wastewater treatment due to its high photocatalytic activity and it can remove various harmful organic pollutants effectively. Under heated system, however, TiO₂ is prone to agglomeration that decrease its abilities as a photocatalyst. In order to overcome the agglomeration and increase its thermal resistance, addition of silica (SiO₂) as supporting material is proposed in this research. Silica or silicon dioxide can be extracted from natural resources such as beach sand. Here, we report the application of a composite photocatalyst of TiO₂/SiO₂ to remove phenolic compounds in wastewater. The photocatalyst was synthesized by adding SiO₂ from beach sand onto TiO₂ through impregnation methods. The results of the X-ray diffraction (XRD) showed that TiO₂ was present in the anatase phase. The highest crystallinity was obtained by TiO₂/SiO₂ ratios of 7:1. SEM results showed that the shape of the particles was spherical. Further characterizations were conducted using Fourier-transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) analysis, and a particle size analyzer (PSA). By using the optimized condition, 96.05% phenol was degraded by the synthesized photocatalyst of TiO₂/SiO₂, under UV irradiation for 120 min. The efficiency of the TiO₂/SiO₂ is 3.5 times better than commercial TiO₂ P25 for the Langmuir–Hinshelwood first-order kinetic model.

The danger from the content of dyes produced by textile-industry waste can cause environmental degradation when not appropriately treated. However, existing waste-treatment methods have not been effective in degrading dyes in textile waste. Zero-valent iron (ZVI), which has been widely used for wastewater treatment, needs to be developed to acquire effective green production. Tea (Camellia sinensis) leaves contain many polyphenolic compounds used as natural reducing agents. Therefore, this study aims to synthesize ZVI using biological reducing agents from tea-leaf extract and apply the Fenton method to degrade the color mixture of rhodamine B and methyl orange. The results show that the highest polyphenols were obtained from tea extract by heating to 90 °C for 80 min. Furthermore, PSA results show that ZVI had a homogeneous size of iron and tea extract at a volume ratio of 1:3. The SEM-EDS results show that all samples had agglomerated particles. The ZVI 1:1 showed the best results, with a 100% decrease in the color intensity of the dye mixture for 60 min of reaction and a degradation percentage of 100% and 66.47% for rhodamine B and methyl orange from LC-MS analysis, respectively. Finally, the decrease in COD value by ZVI was 92.11%, higher than the 47.36% decrease obtained using Fe(II).

This study aims to synthesize Au/TiO₂/Na₂Ti₆O₁₃ composites to reduce the occurrence of recombination and increase photocatalytic activity in phenol degradation. Gold was used due to its high stability and strong surface plasmon resonance (SPR) properties which make it operate effectively in the visible light spectrum. The prepared composites were characterized using XRD, SEM, TEM, FTIR, and DRS. The results showed that the composite consisted of rutile TiO₂ with a crystal size of 38–40 nm and Na₂Ti₆O₁₃ with a crystal size of 25 nm. The gold in the composite has a crystallite size of 16–19 nm along with the percentage of gold added. Morphological analysis shows that the composite has the form of inhomogeneous spherical particles with gold spread among composites with sizes less than 20 nm. FTIR analysis showed the presence of Na–O and Ti–O–Ti bonds in the composite. The best composite was 3% Au/TiO₂/Na₂Ti₆O₁₃ which had high crystallinity, small particle size, and bandgap energy of 2.59 eV. Furthermore, it had an efficiency 205% better than without gold. After that, cost estimation is proposed as a large-scale application. This study describes the total cost, break-even analysis, and payback analysis for the commercialization needs of the designed photocatalytic catalyst.