Amorphous and More Active: The electrochemical generation of hydrogen from water could help in the storage of energy generated by renewable resources at off-peak times. However, catalysts for the slow step of this reaction, the oxygen evolution reaction (OER), are based on oxides of noble metals (iridium and ruthenium) that have limited abundance. A strategy for improving the performance of earth-abundant elements is to explore mixed-metal oxides and to prepare these as amorphous phases.
Smith
et al. (p. 60 , published online 28 March) developed a general method for preparing amorphous oxides, based on photodecomposition of organometallic precursors. Amorphous mixed-metal oxides of iron, nickel, and cobalt were more active than comparable crystalline materials and provided OER performance comparable to noble metal oxides.
24 July 2013 in Journal of the American Chemical Society
We predict and experimentally demonstrate that in a medium with externally induced anisotropy, a wave source of a sufficiently small size can excite practically nondiffractive wave beams with stable subwavelength transverse aperture. The direction of beam propagation is controlled by rotating the induced anisotropy axis. Nondiffractive wave beam propagation, reflection, and scattering, as well as beam steering have been directly observed by optically probing dipolar spin waves in yttrium iron garnet films, where the uniaxial anisotropy was created by an in-plane bias magnetic field.