Coal-based activated carbons (CACs) have excellent valuable applications, and have been industrially produced. However, ultra-fine coal-based activated carbons (UCACs) and their removal of methylene blue (MB) have rarely been reported in the present literature. Two kinds of UCACs were obtained in this paper and the adsorption test of MB was carried out. The adsorption performance of MB on UCAC was simulated by Grand Canonical Monte Carlo (GC-MC) method. The experimental results were validated by molecular simulation, and the adsorption mechanism was investigated. The adsorption amount of MB, the d50, and specific surface area values of the UCACnew (obtained by the new method) and UCACcm (obtained by the conventional chemical method) were 746.95 mg/g, 12.54 μm, 1225.36 m2/g and 652.77 mg/g, 12.10 μm, 713.76 m2/g, respectively. The results of the molecular simulation calculations were consistent with the pattern of magnitude of the experimental results. The peak of the adsorption concentration occurred near 6 Å on the pore surface. The interaction energy of MB molecules with carboxyl groups was much larger than with hydroxyl groups. Van der Waals forces dominated the adsorption process, with a contribution of >60% in both cases.
Three products hyrdrocyclone screen (TPHS) has been proposed for particle separation based on size. In TPHS, a cylindrical screen was embedded in a conventional hydrocyclone (CH) to combine the centrifugal classification and screening to particle separation based on size. The industrial application of TPHS indicates its better device performance than CH. Although, the earlier studies reveal some common understanding for TPHS, the information of the absent air column remains unknown. Hence, the combination of physical experiment and numerical simulation was considered involving a 75 mm TPHS for this knowledge gap. First, both the computational fluid dynamics (CFD) simulation with Reynolds stress mode and the physical experiment with a high-definition camera illustrate the development process details of a flow field in TPHS. That is, the water was imported along the tangential inlet into TPHS; then under the effects of the feed chamber wall and gravity, the liquid phase spiraled downward until the cylindrical screen passed through the sieve; as the liquid moved to the spigot, it could be discharged in time due to the small underflow port, thus the volume fraction of air rapidly reduced from 1 to 0; subsequently the water filled the TPHS and the absent air column could be observed. Furthermore, the distribution comparisons of air volume fraction and static pressure show that TPHS displayed the absent air core with the negative static pressure in the center region along the z-axis, while CH displayed the opposite features. In addition, despite the different inlet velocity, TPHS consistently presented the vanished air column which could be ascribed to the fact that the present cylindrical screen resulted in positive static pressure distribution inside TPHS.
21 January 2021 in Journal of Control Science and Engineering
This paper proposes a fuzzy comprehensive evaluation of ultrafine powders, namely, yield and quality value-based feature selection. Three indicators reflecting product yield and quality were selected to construct a simple and practical fuzzy comprehensive evaluation protocol. The weight set of the indices and the fuzzy evaluation set were calculated based on the analytic hierarchy process (AHP) method. The fuzzy comprehensive evaluation value was worked out as the only comprehensive index for the evaluation of product. The best ultrafine comminution condition will be established through the comparison of the fuzzy comprehensive evaluation values. Single-factor experiments and orthogonal experiments of the main influencing factors of ultrafine comminution were conducted. It was concluded that the importance of each factor is sequentially the concentration, specific surface area (SSA) of the media, and percentage of critical speed (PCS). Moreover, the concentration and SSA of the media were equally important. Ultrafine comminution by ball mill had the best overall performance under the PCS of 85, the SSA of the media of 0.24m2/kg, and the concentration of 75.
15 January 2022 in Journal of Applied Spectroscopy