The working substance fueling a quantum heat engine may contain coherence in its energy basis, depending on the dynamics of the engine cycle. In some models of quantum Otto heat engines, energy coherence has been associated with entropy production and quantum friction. We considered a quantum Otto heat engine operating at finite time. Coherence is generated and the working substance does not reach thermal equilibrium after interacting with the hot heat reservoir, leaving the working substance in a state with residual energy coherence. We observe an interferencelike effect between the residual coherence (after the incomplete thermalization) and the coherence generated in the subsequent finite-time stroke. We introduce analytical expressions highlighting the role of coherence and examine how this dynamical interference effect influences the engine performance. Additionally, in this scenario in which coherence is present along the cycle, we argue that the careful tuning of the cycle parameters may exploit this interference effect and make coherence acts like a dynamical quantum lubricant. To illustrate this, we numerically consider an experimentally feasible example and compare the engine performance to the performance of a similar engine where the residual coherence is completely erased, ruling out the dynamical interference effect.

We introduce a two-qubit engine that is powered by entanglement and local measurements. Energy is extracted from the detuned qubits coherently exchanging a single excitation. Generalizing to an $N$-qubit chain, we show that the low energy of the first qubit can be up-converted to an arbitrarily high energy at the last qubit by successive neighbor swap operations and local measurements. We finally model the local measurement as the entanglement of a qubit with a meter, and we identify the fuel as the energetic cost to erase the correlations between the qubits. Our findings extend measurement-powered engines to composite working substances and provide a microscopic interpretation of the fueling mechanism.

The extension of quantum thermodynamics to situations that go beyond standard thermodynamic settings comprises an important and interesting aspect of its development. One such situation is the analysis of the thermodynamic consequences of structured environments that induce a non-Markovian dynamics. We study a quantum Otto refrigerator where the standard Markovian cold reservoir is replaced by a specific engineered cold reservoir which may induce a Markovian or non-Markovian dynamics on the quantum refrigerant system. The two dynamical regimes can be interchanged by varying the coupling between the refrigerant and the reservoir. An increase of non-Markovian effects will be related to an increase of the coupling strength, which in turn will make the energy stored in the interaction Hamiltonian, the interaction energy, increasingly relevant. We show how the figures of merit, the coefficient of performance, and the cooling power change for non-negligible interaction energies, discussing how neglecting this effect would lead to an overestimation of the refrigerator performance. Finally, we also consider a numerical simulation of a spin quantum refrigerator with experimentally feasible parameters to better illustrate the non-Markovian effects induced by the engineered cold reservoir. We argue that a moderate non-Markovian dynamics performs better than either a Markovian or a strong non-Markovian regime of operation.

We present an autonomous Maxwell's demon scheme. It is first analyzed theoretically in terms of information exchange in a closed system and then implemented experimentally with a single Rydberg atom and a high-quality microwave resonator. The atom simulates both a qubit interacting with the cavity and a demon carrying information on the qubit state. While the cold qubit crosses the hot cavity, the demon prevents energy absorption from the cavity mode, apparently violating the second law of thermodynamics. Taking into account the change of the mutual information between the demon and the qubit-cavity system gives rise to a generalized expression of the second law that we establish and measure. Finally, considering the closed qubit-cavity-demon system, we establish and measure that the generalized second law can be recast into an entropy conservation law, as expected for a unitary evolution.

We propose an operational scenario to characterize the nature of energy exchanges between two coupled but otherwise isolated quantum systems. Defining work as the component stemming from effective unitary interactions performed by each system on one another, the remnant is stored in the correlations and generally prevents full energy extraction by local operations. Focusing on the case of a qubit coupled to the light field of a waveguide, we establish a bound relating work exchange and local energy extraction when the light statistics is coherent, and that gets violated in the presence of a quantum light pulse. Our results provide operational, energy-based witnesses to probe nonclassical resources.

Obtaining the total wavefunction evolution of interacting quantum systems provides access to important properties, such as entanglement, shedding light on fundamental aspects, e.g., quantum energetics and thermodynamics, and guiding towards possible application in the fields of quantum computation and communication. We consider a two-level atom (qubit) coupled to the continuum of travelling modes of a field confined in a one-dimensional chiral waveguide. Originally, we treated the light-matter ensemble as a closed, isolated system. We solve its dynamics using a collision model where individual temporal modes of the field locally interact with the qubit in a sequential fashion. This approach allows us to obtain the total wavefunction of the qubit-field system, at any time, when the field starts in a coherent or a single-photon state. Our method is general and can be applied to other initial field states.