Phanerozoic orogenic gold mineralization at craton margins is related to the metasomatism of the lithospheric mantle by crustal material. Slab subduction transfers Au from the crust to the metasomatized mantle and oxidizes the latter to facilitate the mobilization of Au into mantle melts. The role of volatiles in the mobilization of Au in the mantle is unclear because of the absence of direct geochemical evidence relating the mantle source of Au to Au mineralization in the overlying crust. This study uses lithium isotopes from a large suite of lamprophyres to characterize the mantle beneath the eastern North China Craton, which hosts giant Mesozoic gold deposits. Our results indicate a strong genetic link between carbonate metasomatism in the mantle and Au mineralization in the overlying crust. Although pre-enrichment of Au in the mantle is critical for forming giant Au provinces, the oxidation of the lithospheric mantle controls the mobilization of Au.

Investigation of Hg isotope ratios of gold-related sulfides and penecontemporaneous mafic dikes from four orogenic gold provinces on the margins of the North China Craton and Yangtze Craton identifies three orogenic gold deposit (OGD) groups from different tectonic regimes. Ore-related sulfides of group 1 OGDs and mafic dikes from the craton margin reworked via oceanic subduction mostly have positive Δ¹⁹⁹Hg values. The group 2 OGDs and mafic dikes from the margin that witnessed complex oceanic and continental subductions have mixed positive to negative Δ¹⁹⁹Hg values. The group 3 OGDs on the margin that experienced continental subduction have dominantly negative Δ¹⁹⁹Hg values. These isotopic differences indicate subduction histories have a first-order control on the distinct sources for the OGDs. It indicates that OGDs were derived from fluids from the mantle lithosphere metasomatized by contrasting subduction components, not from metamorphic fluids as is widely accepted. Group 1 OGDs and dikes were sourced from metasomatized mantle, which inherited the positive Δ¹⁹⁹Hg of both recycled marine sediments and seawater during oceanic subduction, whereas group 3 with negative Δ¹⁹⁹Hg was derived from mantle lithosphere metasomatized by subduction of mainly continental components. This genetic model identifies regions with high-grade metamorphic rocks above metasomatized mantle lithosphere as promising new OGD exploration targets.

The Danba gold deposit is located in a poorly-documented gold province on the north-western margin of the Yangtze Craton. It is sited in Devonian sequences in a high-grade metamorphic terrane that includes an extensional metamorphic core complex. Around the deposit, peak metamorphic conditions of 6 ± 0.5 kbar and 650 ± 50 °C at ca. 193 Ma were followed by retrograde sillimanite-grade conditions of 4.5 ± 0.5 kbar and 550 ± 50 °C. The deposit is hosted in a broadly strata-bound ductile-brittle shear zone with high-T proximal alteration assemblages of biotite-amphibole-plagioclase and ore assemblages dominated by pyrrhotite, but with a strong association between gold and bismuth tellurides. Alteration mineral thermobarometers, together with heating/freezing studies of low-salinity H₂O–CO₂–CH₄ fluid inclusions, indicate P-T conditions of early ore deposition of approximately 4–5 kbar and 500–650 °C at around 185 ± 9 Ma indicated by Re-Os geochronology on ore-related molybdenite. In conjunction, all data demonstrate that Danba represents a Lower Jurassic hypozonal orogenic gold deposit that formed during post-peak metamorphic retrogression. The primary high P-T nature of the deposit, combined with its late-metamorphic timing, negate that the ore fluid was sourced via devolatilization of the hosting supracrustal sequences. A deep externally-derived ore-fluid source is required. The most likely source is the K–H₂O–CO₂ and ore-metal fertilized lithospheric mantle that was metasomatized during Neoproterozoic subduction. It is proposed that transition from lithospheric transpression to extension in the Jurassic triggered the devolatilization of this metasomatized lithosphere to cause the formation of this rare Phanerozoic amphibolite-hosted gold deposit at Danba.