We show that the low-frequency absorbance of undoped graphene, silicene, and germanene has a universal value, only determined by the Sommerfeld fine-structure constant. This result is derived by means of ab initio calculations of the complex dielectric function for optical interband transitions applied to two-dimensional (2D) crystals with honeycomb geometry. The assumption of chiral massless Dirac fermions is not necessary. The low-frequency absorbance does not depend on the group-IV atom, neither on the sheet buckling nor on the orbital hybridization. We explain these findings via an analytical derivation of the relationship between absorbance and fine-structure constant for 2D Bloch electrons. The effect of deviations of the electronic bands from linearity is also discussed.
Calculating the complex dielectric function for optical interband transitions we show that the two-dimensional crystals silicene and germanene possess the same low-frequency absorbance as graphene. It is determined by the Sommerfeld finestructure constant. Deviations occur for higher frequencies when the first interband transitions outside K or K′ contribute. The low-frequency results are a consequence of the honeycomb geometry but do not depend on the group-IV atom, the sheet buckling, and the orbital hybridization. The two-dimensional crystals may be useful as absorption normals in silicon technology.
An accurate assessment of a building’s wall performance, defined through the thermal transmittance, is essential to compute the annual energy consumption. Analyzing opaque surfaces, the heat transfer across walls can be modeled by an electro-thermal analogy, based on resistors series, crossed by a one-dimensional heat flow. This analogy is well established and it refers to stratigraphy composed of homogeneous materials. When dealing with inhomogeneous materials, possibly including hollow bricks, the wall’s thermal transmittance is evaluated by means of an effective conductance. However, in order to verify the theoretical models effectiveness, a comparison with in situ measurements is needed. In this paper, three building walls characterized by different stratigraphy have been analyzed; by employing a heat flow meter investigation. Measurements results and estimated thermal transmittance values—calculated applying the standard UNI EN ISO 6946—have been compared.