Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, the supercritical state of water is still not well understood. Recent theories predict that liquid-like (LL) and gas-like (GL) supercritical water are metastable phases, and that the so-called Widom line zone is marking the crossover between LL and GL behavior of water. With neutron imaging techniques, we succeed to monitor density fluctuations of supercritical water while the system evolves rapidly from LL to GL as the Widom line is crossed during isobaric heating. Our observations show that the Widom line of water can be identified experimentally and they are in agreement with the current theory of supercritical fluid pseudo-boiling. This fundamental understanding allows optimizing and developing new technologies using supercritical water as a solvent.
The present review paper focuses on selected cases around the world of land subsidence phenomena caused by the overexploitation of aquifers. Land subsidence is closely related to human activity. In particular, the development of technology has led to an exponential increase in industrial and agricultural production, as well as extensive urbanization, mainly in large cities. The action of those parameters, along with the effects of climate change, has led to further increases in water demands, which have mainly been served by overexploitation of the aquifers. Overexploitation, in conjunction with broader geo-tectonic conditions, can trigger severe land subsidence phenomena, resulting in significant damage affecting the physical and man-made environment. The scope of the present study is to provide a critical review of the existing literature on land subsidence due to aquifer overexploitation and highlight the main causal factors driving this process. The methods developed in the past and their outcomes hold significant importance in sustainable development strategic planning.
The thermal insulation properties of building walls are critical to the overall energy efficiency and comfort of a building. One important factor that can affect these properties is the type of bricks used in construction. Bricks can vary in their geometry and thermal coefficient, which can impact their ability to transfer heat through the wall. The geometry of a brick can affect its thermal properties by altering the amount of air trapped within it and the surface area available for heat transfer. Hollow bricks or those with complex geometries may have lower thermal conductivity than regular solid bricks due to the air pockets trapped within them. Conversely, larger surface areas on the exterior of the brick can increase heat transfer. The thermal coefficient of clay, a common material used in brick production, is another important factor. Clay has relatively low thermal conductivity, meaning it is a poor conductor of heat. However, the quality of the clay, as well as the firing temperature and duration used in brick production, can impact its thermal coefficient. Higher firing temperatures and longer firing times can result in a more compact and dense clay brick, which can improve its thermal properties. In summary, the thermal insulation properties of building walls can be significantly affected by the type of bricks used in their construction. It is important to consider the geometry and thermal coefficient of the bricks when designing a building to achieve the desired level of thermal insulation. By selecting bricks with appropriate properties, designers can help to improve the energy efficiency and comfort of the building while reducing its environmental impact.
A transient mathematical model was developed for the description of fluid flow, heat transfer and electromagnetic phenomena involved in the production of ferronickel in electric arc furnaces. The key operating variables considered were the thermal and electrical conductivity of the slag and the shape, immersion depth and applied electric potential of the electrodes. It was established that the principal stimuli of the velocities in the slag bath were the electric potential and immersion depth of the electrodes and the thermal and electrical conductivities of the slag. Additionally, it was determined that, under the set of operating conditions examined, the maximum slag temperature ranged between 1756 and 1825 K, which is in accordance with industrial measurements. Moreover, it was affirmed that contributions to slag stirring due to Lorentz forces and momentum forces due to the release of carbon monoxide bubbles from the electrode surface were negligible.
A computational fluid dynamics (CFD) method is proposed to analyze the operation of a submerged electric arc furnace (SAF) used in ferronickel production. A three-dimensional mathematical model was used for the time-dependent solution of the fluid flow, heat transfer and electromagnetic phenomena. The slag's physical properties, which play a crucial role in the SAF operation, were previously determined using classical molecular dynamics simulations and empirical relationships. The analysis revealed that the main slag properties affecting SAF operation are density, viscosity and electrical conductivity—the latter two being mutually dependent. The high electrical conductivity values of the slag favor melting via the high Joule heat produced within the slag region. Calculation of the dimensionless Péclet and Reynolds numbers revealed that the slag velocities play a decisive role in heat transfer and further indicate that the slag flow is laminar. The average slag velocity calculated 0.0001 m/s with maxima in the vicinity of the electrodes.