This article addresses the state of the art of bioleaching research published in South Korean Journals. Our research team reviewed the available articles registered in the Korean Citation Index (KCI, Korean Journal Database) addressing the relevant aspects of bioleaching. We systematically categorized the target metal sources as follows: mine tailings, electronic waste, mineral ores and metal concentrates, spent catalysts, contaminated soil, and other materials. Molecular studies were also addressed in this review. The classification provided in the present manuscript details information about microbial species, parameters of operation (e.g., temperature, particle size, pH, and process length), and target metals to compare recoveries among the bioleaching processes. The findings show an increasing interest in the technology from research institutes and mineral processing-related companies over the last decade. The current research trends demonstrate that investigations are mainly focused on determining the optimum parameters of operations for different techniques and minor applications at the industrial scale, which opens the opportunity for greater technological developments. An overview of bioleaching of each metal substrate and opportunities for future research development are also included.
Silicate mesoporous materials were synthesized with nonionic surfactant and their surfaces were modified by oleic acid adsorption. Infrared spectrometer, nitrogen adsorption‐desorption isotherm, scanning electron microscopy, and thermogravimetric analyses were used to investigate the structure of oleic acid modified mesoporous material. The effects of heat treatment at various temperatures on oleic acid modified materials were also studied. Oleic acids on silica surfaces were found to be bonded chemically and/or physically and be capable of enduring up to 180°C. The adsorbed oleic acid improved the hydrothermal stability of mesoporous silica and assisted mesopore structure to grow more in hydrothermal treatment process by preventing the approach of water.
1 January 2012 in International Journal of Environmental Science and Development
The addition of ferrous sulfate as a depressant for Ca-bearing minerals such as calcite and fluorite during scheelite flotation was investigated to recover scheelite from tungsten mine tailings, using Hallimond-tube flotation tests, zeta-potential measurement and Fourier-transform infrared (FT-IR) analyses. The flotation tests indicate that the selectivity of scheelite recovery was the largest over calcite and fluorite under the following conditions: 0.5 g sample, 50 g/ton AF65, 1 × 10−3 M sodium oleate, 1200 g/ton SF2 (sodium silicate and ferrous sulfate) depressant with the 8:2 ratio of sodium silicate and ferrous sulfate, 50 mL/min air injection rate, 5 min flotation time, and pH 8. The selectivity of scheelite flotation increased when the amount of SF2 depressant addition increased to 1200 g/ton, but it decreased by adding 1400 g/ton SF2, which would result from the precipitation of iron components. In the zeta potential results, the zeta potentials of scheelite with the collector show similar results regardless of the addition of SF2, while the change of zeta potentials of calcite and fluorite by adding NaO collector diminished when SF2 was added. In FT-IR analyses, the spectrum of NaO in scheelite results was observed regardless of the addition of SF2, while the spectra of NaO in calcite and fluorite results disappeared when SF2 was added. These results suggest that the addition of SF2 prevents the adsorption of NaO on the surface of calcite and fluorite. Therefore, the addition of SF2 could enhance the selectivity of scheelite flotation over calcite and fluorite.
1 August 2018 in Journal of the Korean Society of Mineral and Energy Resources Engineers