Poly(lactic acid) (PLA) is a green alternative to petrochemical commodity plastics, used in packaging, agricultural products, disposable materials, textiles, and automotive composites. It is also approved by regulatory authorities for several biomedical applications. However, for some uses it is required that some of its properties be improved, namely in terms of thermo-mechanical and electrical performance. The incorporation of nanofillers is a common approach to attain this goal. The outstanding properties of carbon-based nanomaterials (CBN) have caused a surge in research works dealing with PLA/CBN composites. The available information is compiled and reviewed, focusing on PLA/CNT (carbon nanotubes) and PLA/GBM (graphene-based materials) composites. The production methods, and the effects of CBN loading on PLA properties, namely mechanical, thermal, electrical, and biological, are discussed.
Natural cork stopper manufacturing produces a significant amount of cork waste, which is granulated and combined with synthetic glues for use in a wide range of applications. There is a high demand for using biosourced polymers in these composite materials. In this study, xanthan gum (XG) and chitosan (CS) were investigated as possible natural binders for cork. Xanthan gum was oxidized at two different aldehyde contents as a strategy to improve its water resistance. This modification was studied in detail by 1H and 13C nuclear magnetic resonance (NMR), and the degree of oxidation was determined by the hydroxylamine hydrochloride titration method. The performance of the adhesives was studied by tensile tests and total soluble matter (TSM) determinations. Xanthan gum showed no water resistance, contrary to oxidized xanthan gum and chitosan. It is hypothesized that the good performance of oxidized xanthan gum is due to the reaction of aldehyde groups—formed in the oxidation process—with hydroxyl groups on the cork surface during the high temperature drying. Combining oxidized xanthan gum with chitosan did not yield significant improvements.
Particleboard (PB), medium density fibreboard (MDF), oriented strand board (OSB) and plywood (PW), the most common products of wood panel industry, are produced by means of synthetic adhesives (resins). From the wide range of adhesives employed, amino resins as combination of formaldehyde (F) and urea (U), and melamine (M) are the most important ones, which include the most popular UF and MUF resins. This review is an introduction to the UF and MUF synthesis processes, and also addresses the key parameters for the performance of these adhesives and gives an overview about the final characteristics of PB and MDF prepared with amino resins. The characterization methods for amino resins and panels are outlined. The strategies for the optimization of resin properties and pressing conditions are discussed in terms of their good performance also under conditions of low formaldehyde emission.