The actual combustion rate of pulverized coal in the blast furnace tuyere is hard to be measured. In this research, the combustion rate of pulverized coal injected into oxygen blast furnace was obtained by a new equipment. This equipment can simulate the actual blast furnace well, and the relationship between pulverized coal injection (PCI) ratio and
A
O/C was established by mathematical deduction. The experimental results show that the best combustibility of the four pulverized coals is C, and when the coal injection ratio is 350 kg/tHM, the combustion rate can be reached 79%, while the combustion rate of B in the same case is only 45.6%. With the increase of
A
O/C , the relative amount of oxygen to coal increases, the combustion conditions become better, and combustion rate of the pulverized coal increases. In addition, under the condition of high temperature and rapid combustion, with the increase of coal’s volatile, the combustion rate increases and the corresponding PCI ratio is also increased. By using the new equipment, the unburned coal under the oxygen blast furnace conditions can be collected for further study.
In recent years, the concept of green, low-carbon and clean energy consumption has been deeply rooted in the hearts of the people, and countries have actively advocated the use of new energy. In the face of problems such as resource shortage and environmental pollution, we began to explore the use of new fuels instead of coal for production. Biomass resources have the characteristics of being renewable and carbon neutral and having large output. As an energy utilization, it is helpful to promote the transformation of the energy structure in various countries. Applying it to ironmaking production is not only conducive to energy conservation and emission reduction in the ironmaking process but also can achieve efficient utilization of crop waste. By introducing the source and main preparation methods of biochar, this paper expounds the main links and advantages of biochar in the ironmaking process and puts forward the direction of biochar in ironmaking in the future.
8 June 2023 in Journal of Iron and Steel Research International
The composition of Bayan Obo iron ore concentrate is complex. If a large proportion is used to prepare pellets, abnormal swelling will occur during blast furnace smelting. This paper studies the swelling behavior of pellets prepared from Bayan Obo iron ore concentrate in stages during the reduction process; XRD and SEM-EDS analysis and calculates the crystal parameters of the reduction products in each stage. The results show that the total RSI of pellets prepared from Bayan Obo iron ore concentrate is as high as 35%, and the third stage of reduction has the maximum swelling rate, which is 24%. The mechanisms of the three stages reduction swelling of pellets are the crystal transformation, the effect of slag phase and the growth of iron whiskers. The results can enrich the reduction swelling theory of pellets prepared from complex intergrowth minerals.
Metallurgical dust and sludge are solid waste resources with recycling value. In recent years, rotary hearth furnace has become the most important means to treat metallurgical dust and sludge because of its wide range of raw materials and strong treatment capacity. In this study blast furnace ash and converter sludge were selected as the research objects, and high-quality metallized pellets were prepared based on the rotary hearth furnace process. The strength changed of pellets, the reduction process of iron oxides and the removal process of zinc during the roasting of pellets in rotary hearth furnace were studied. To explore the reasonable roasting condition for preparing metallized pellets in rotary hearth furnace. The optimum roasting temperature of the pellets was 1250℃ and the roasting time was 25 min. The compressive strength, metallization rate and dezincification rate of metallized pellets reached 1361N, 97.44% and 95.67%, respectively. The efficient resource utilization of various metallurgical dust and sludge is realized.
To explore the reduction swelling process of pellets prepared from the Bayan Obo iron ore concentrate, based on the iron oxide reduction theory of pellets, the reduction of pellets prepared from the Bayan Obo iron ore concentrate was analyzed by thermogravimetric experiments and kinetic calculations in three stages. The reason for the abnormal swelling of pellets prepared from the Bayan Obo iron ore concentrate was analyzed from the perspective of kinetics. The research results showed that carbon deposition occurred in the first stage of reduction. The second stage of reduction was controlled by an interfacial chemical reaction, and the activation energy of the reaction was 117.99 kJ/mol. The reaction energy barrier was higher and the reaction rate was slower, and therefore, the reduction swelling rate of pellets was lower at this stage. The third stage of reduction was controlled by internal diffusion, and the reaction activation energy was 15.9 kJ/mol. The reduction reaction of pellets occurs violently, and the reduction swelling behavior was remarkable at this stage.