Silicon-based tandem solar cells incorporating low-cost, abundant, and non-toxic metal oxide materials can increase the conversion efficiency of silicon solar cells beyond their conventional limitations with obvious economic and environmental benefits. In this work, the electrical characteristics of a metal oxide thin-film heterojunction solar cell based on a cuprous oxide (Cu₂O) absorber layer were investigated. Highly Al-doped n-type ZnO (AZO) and undoped p-type Cu₂O thin films were prepared on quartz substrates by magnetron sputter deposition. The electrical and optical properties of these thin films were determined from Hall effect measurements and spectroscopic ellipsometry. After annealing the Cu₂O film at 900 °C, the majority carrier (hole) mobility and the resistivity were measured at 50 cm²/V·s and 200 Ω·cm, respectively. Numerical modeling was carried out to investigate the effect of band alignment and interface defects on the electrical characteristics of the AZO/Cu₂O heterojunction. The analysis suggests that the incorporation of a buffer layer can enhance the performance of the heterojunction solar cell as a result of reduced conduction band offset.

Cuprous oxide (Cu₂O) is a p-type semiconductor with high optical absorption and a direct bandgap of about 2.1 eV, making it an attractive material for photovoltaic applications. For a high-performance photovoltaic device, the formation of low-resistivity contacts on Cu₂O thin films is a prerequisite, which can be achieved by, for instance, nitrogen doping of Cu₂O in order to increase the carrier concentration. In this work, nitrogen-doped p-type Cu₂O thin films were prepared on quartz substrates by magnetron sputter deposition. By adding N₂ gas during the deposition process, a nitrogen concentration of up to 2.3 × 10²¹ atoms/cm³ in the Cu₂O thin films was achieved, as determined from secondary ion mass spectroscopy measurements. The effect of nitrogen doping on the structural, optical, and electrical properties of the Cu₂O thin films was investigated. X-ray diffraction measurements suggest a preservation of the Cu₂O phase for the nitrogen doped thin films, whereas spectrophotometric measurements show that the optical properties were not significantly altered by incorporation of nitrogen into the Cu₂O matrix. A significant conductivity enhancement was achieved for the nitrogen-doped Cu₂O thin films, based on Hall effect measurements, i.e., the hole concentration was increased from 4 × 10¹⁵ to 3 × 10¹⁹ cm⁻³ and the resistivity was reduced from 190 to 1.9 Ω⋅cm by adding nitrogen to the Cu₂O thin films.

This study is aimed at increasing the performance and reliability of silicon-based heterojunction solar cells with advanced methods. This is achieved by a numerical electro-optical modeling and reliability analysis for such solar cells correlated with experimental analysis of the Cu₂O absorber layer. It yields the optimization of a silicon tandem heterojunction solar cell based on a ZnO/Cu₂O subcell and a c-Si bottom subcell using electro-optical numerical modeling. The buffer layer affinity and mobility together with a low conduction band offset for the heterojunction are discussed, as well as spectral properties of the device model. Experimental research of N-doped Cu₂O thin films was dedicated to two main activities: (1) fabrication of specific samples by DC magnetron sputtering and (2) detailed characterization of the analyzed samples. This last investigation was based on advanced techniques: morphological (scanning electron microscopy—SEM and atomic force microscopy—AFM), structural (X-ray diffraction—XRD), and optical (spectroscopic ellipsometry—SE and Fourier-transform infrared spectroscopy—FTIR). This approach qualified the heterojunction solar cell based on cuprous oxide with nitrogen as an attractive candidate for high-performance solar devices. A reliability analysis based on Weibull statistical distribution establishes the degradation degree and failure rate of the studied solar cells under stress and under standard conditions.