We report that the Zn-terminated ZnO (0001) polar surface is chemically active and the oxygen-terminated polar surface is inert in the growth of nanocantilever arrays. Longer and wider “comblike” nanocantilever arrays are grown from the (0001)-Zn surface, which is suggested to be a self-catalyzed process due to the enrichment of Zn at the growth front. The chemically inactive surface typically does not initiate any growth, but controlling experimental conditions could lead to the growth of shorter and narrower nanocantilevers from the intersections between with surfaces.
Atomic imaging of three-dimensional structures has required a crystal in diffraction or a lens in electron imaging. Whereas diffraction achieves very high resolution by averaging over many cells, imaging gives localized structural information, such as the position of a single dopant atom. However, lens aberrations limit electron imaging resolution to about 1 angstrom. Resolution is reduced further by low contrast from weakscattering or from the limitations on electron dose for radiation-sensitive molecules. We show that both high resolution and high contrast can be achieved by imaging from diffraction with a nanometer-sized coherent electron beam. The phase problem is solved by oversampling and iterative phase retrieval. We apply this technique to image a double-wall carbon nanotube at 1-angstrom resolution, revealing the structure of two tubes of different helicities. Because the only requirement for imaging is a diffraction pattern sampled below the Nyquist frequency, our technique has the potential to image nonperiodic nanostructures, including biological macromolecules, at diffraction intensity–limited resolutions.
12 July 2005 in Journal of the American Chemical Society
A superconducting interface: Interfaces between materials can harbor quantum states that belong to neither of the materials. A classic example is the superconducting interface between two insulating oxides, LaAlO 3 and SrTiO 3 , with a critical temperature of around 200 millikelvin. Liu et al. observed superconductivity at a different interface—formed between KTaO 3 as a substrate and an overlayer of either EuO or LaAlO 3 —at a considerably higher temperature of about 2 kelvin. Transport measurements displayed anisotropy, which may indicate an unusual superconducting state. Science , this issue p. 716