Chile is a fast-growing country with important industrial activities near urban areas. In this study, the mass and elemental concentrations of PM10 and PM2.5 were measured in five major Chilean urban areas. Samples of particles with diameter less than 10 microm (PM10) and 2.5 microm (PM2.5) were collected in 1998 in Iquique (northern Chile), Valparaiso, Viña del Mar, Rancagua (central Chile), and Temuco (southern Chile). Both PM10 and PM2.5 annual mean concentrations (PM10: 56.9-77.6 microg/m3; PM2.5: 22.4-42.6 microg/m3) were significantly higher than the corresponding European Union (EU) and U.S. Environmental Protection Agency (EPA) air quality standards. Moreover, the 24-hr PM10 and PM2.5 U.S. standards were exceeded infrequently for some of the cities (Rancagua and Valparaiso). Elements ranging from Mg to Pb were detected in the aerosol samples using X-ray fluorescence (XRF). For each of the five cities, factor analysis (FA) was applied to identify and quantify the sources of PM10 and PM2.5. The agreement between calculated and measured mass and elemental concentrations was excellent in most of the cities. Both natural and anthropogenic sources were resolved for all five cities. Soil and sea were the most important contributors to coarse particles (PM10-PM2.5), whereas their contributions to PM2.5 were negligible. Emissions from Cu smelters and oil refineries (and/or diesel combustion) were identified as important sources of PM2.5, particularly in the industrial cities of Rancagua, Valparaiso, and Viña del Mar. Finally, motor vehicles and wood burning were significant sources of both PM2.5 and PM10 in most of the cities (wood burning was not identified in Iquique).

This article is a review of the science goals and activities initiated within the framework of the Pollution and its Impacts on the South American Cryosphere (PISAC) initiative. Air pollution associated with biomass burning and urban emissions affects extensive areas of South America. We focus on black carbon (BC) aerosol and its impacts on air quality, water availability, and climate, with an emphasis on the Andean cryosphere. BC is one of the key short‐lived climate pollutants that is a topic of growing interest for near‐term mitigation of these issues. Limited scientific evidence indicates that the Andean cryosphere has already responded to climate change with receding glaciers and snow cover, which directly affect water resources, agriculture, and energy production in the Andean region of South America. Despite the paucity of systematic observations along the Andes, a few studies have detected BC on snow and glaciers in the Andes. These, in addition to existing and projected emissions and weather patterns, suggest a possible contribution of BC to the observed retreat of the Andean cryosphere. Here we provide an overview of the current understanding of these issues from scientific and policy perspectives, and propose strategic expansions to the relevant measurement infrastructure in the region.