In the deep mining process of coal seams, the mechanical environment of the coal body is complex and in the state of cyclic loading and unloading. The change in the stress state leads to the change in the pore characteristics and the permeability. To investigate the effects of cyclic loading and unloading on the pore characteristics and the permeability of coal, the seepage experiment was carried out for the coal samples using the self-developed triaxial permeation instrument. By pressure confining and continuous cyclic loading and unloading, the evolution of the porosity and the permeability of the coal samples was investigated. Under the condition of the experiment, the influences of the initial value of the confining pressure and the cyclic load amplitude on the evolution of the permeability and the pore structure characteristics of the coal samples were clarified. The experimental results showed that the porosity and the permeability decreased exponentially with an increase in the number of loading and unloading cycles, and this decreasing trend gradually weakened until the porosity and the permeability became relatively stable. When the cyclic load amplitude was the same and the confining pressure increased, the effective porosity of the coal body and the bound porosity decreased. When the confining pressure was the same and the cyclic load amplitude increased, the effective porosity of the coal body decreased and the bound porosity increased. The loss rate of the permeability of the coal samples increased gradually with an increase in the cyclic load amplitude. The same tendency was observed when the cyclic load amplitude was the same, and the confining pressure was different, while the increasing trend was not so obvious. By analyzing the relationship between the porosity and the permeability of the coal samples under different cyclic loading and unloading paths, it was found that the effective porosity and the permeability of the coal samples conformed to the power–law relationship in the process of cyclic loading and unloading, and the change in the cyclic load amplitude had a significant effect on this relationship. The influences of the cyclic load amplitude and the confining pressure on the stress sensitivity of the coal samples were considered, and the change factor of the stress sensitivity was introduced into the relationship between the porosity and the permeability. This relationship was established considering cyclic loading and unloading.

In view of the problem that excessive CO in underground coal mine space can easily lead to a large number of casualties, Cu-Mn-Sn water-resistant eliminators with different Sn contents were prepared by a co-precipitation method. The activity of the eliminators was analyzed by using an independently developed activity testing platform, N-2 adsorption and desorption, XRD, SEM, XPS, and FTIR to characterize the activity factors and water resistance. The results showed that Cu-Mn-Sn-20 with 20% Sn content had the highest activity, which was 3.23 times that of Cu-Mn. The main reason for the increased activity is that Cu-Mn-Sn-20 doped with 20% Sn provides a larger specific surface area and more active sites and reduces the pore size, so that the crystallization degree of Cu1.4Mn1.5O4 is lower. The doping of 20% Sn reduces the absorption of lattice water and coordination water and improves the water resistance of Cu-Mn-Sn-type eliminators. The Cu-Mn-Sn-20 water-resistant eliminator is used to quickly eliminate CO in underground coal mines, which is of great significance for the rescue workers in underground coal mines after disasters.

The gas pressure generated during a coal and gas outburst is an important factor affecting the stability of mine ventilation systems. The gas released from an outburst flows and diffuses in the mine, leading to an uneven distribution of the air in the mine ventilation system and the formation of natural wind pressure. Because of the effect of the gas pressure, the mine ventilation system becomes disordered, leading to a counter flow in the roadway. This increases the complexity of the gas movement, extends the influence range of the gas, enlarges the disaster area in the mine, and exacerbates the destructiveness. In this study, the TF1M simulation program was applied to simulate a coal and gas outburst accident that occurred in the 1747 heading roadway of the Sizhuang Coal Mine, in a bid to reproduce the entire process of the diffusion flow of the counter current and outburst gas in the mine roadway. Moreover, the dynamic influence of the gas pressure on the entire ventilation network was analyzed. An experimental device was set up to test the relationship between the natural wind pressure and the height difference of the roadway and density of the gas flow, and the formation and mechanism of the natural wind pressure were explored. By analyzing the experimental and numerical results, the variation law of the air flow and the law of gas movement under the influence of gas pressure were summarized. The movement law and influencing factors of the gas during the mine outburst period were studied, the influence range of the gas was determined, the distribution law of the gas concentration after the outburst was obtained, and further expansion of the gas was prevented. This study has theoretical and practical significance in enhancing our understanding of the development process of mine gas disasters, which can help establish effective emergency response strategies and reasonably implement postdisaster relief measures.

Addressing the issue of suffocation and casualties caused by a large amount of poisonous CO gas generated after a gas explosion, research involving an experimental system for the removal of CO using a Cu–Mn elimination agent was studied. The influence of O₂ concentration, temperature, and CO concentration on the elimination performance of the agent after a gas explosion was studied. The quantitative relationship between the amount of CO eliminated, the elimination rate, the O₂ concentration, and temperature was analyzed. Further analysis was completed regarding the influence of O₂ concentration, temperature, and CO concentration on the thermal effect in the elimination process. The results showed that the elimination agent had a rapid effect on the removal of CO. When the ratio of CO concentration to O₂ concentration was closer to the stoichiometric ratio, the elimination and reaction were more complete, the time to complete elimination was shorter, and the peak temperature was higher. As the temperature increased, the time to reach the elimination limit became longer, the elimination rate decreased, the reaction was slower, and the peak temperature was lower. As the CO concentration increased, it was observed that the higher the peak temperature, the longer it took to reach the peak time. The results of the study provide a theoretical support for the catalytic oxidation of CO using the Cu–Mn eliminator after a coal mine gas explosion.

CO in coal mine underground spaces can easily cause casualties among miners. The humidity in coal mines is relatively high, and traditional Cu-Mn catalysts are prone to deactivation. Compared to traditional Cu-Mn catalysts, doping with Sn enhances the activity and water resistance of Cu-Mn catalysts. The Cu-Mn-Sn catalyst was tested using XPS, FTIR, and a self-made Activity Test Experimental System, with partial data processed using the Avantage software. The results show that Sn increases the number of active sites (Cu⁺) on the Cu-Mn catalyst and the proportion of surface adsorbed oxygen (O_ads) and surface lattice oxygen (O_lat) in O 1s, which is the reason for the improved activity of the Cu-Mn-Sn catalyst. Sn weakens the coordination bond between Cu²⁺ and H₂O, reducing the formation of CO₃²⁻, which is the reason for the improved water resistance of the catalyst.