Applications of metal oxide nanoparticles in the agriculture sector are being extensively included as the materials are considered superior. In the present work, zinc oxide nanoparticle (ZnO NPs), with a developing fertilizer, is applied in the fortification of rice grain yield and nutrient uptake enhancement. To evaluate the role of ZnO NP, two field experiments were conducted during the 2018 and 2019 seasons. ZnO NPs were small, nearly spherical, and their sizes equal to 31.4 nm, as proved via the dynamic light scattering technique. ZnO NPs were applied as a fertilizer in different concentrations, varying between 20 and 60 mg/L as a foliar spray. The mixture of ZnSO₄ and ZnO NP₄₀ ameliorated yield component and nutrients (N, K, and Zn) uptake was enhanced compared to traditional ZnSO₄ treatment. Nevertheless, the uptake of the phosphorous element (P) was adversely affected by the treatment of ZnO NPs. Thus, treatment via utilizing ZnO NPs as a foliar with a very small amount (40 ppm) with of basal ZnSO₄ led to a good improvement in agronomic and physiological features; eventually, higher yield and nutrient-enriched rice grain were obtained.

Water stress is considered one of the most environmental hazards that threaten agricultural productivity. Therefore, two field experiments were conducted to investigate the impact of biochar (6 t ha⁻¹ as soil amendment), ZnO NPs (50 mg L⁻¹ as foliar application), and their combination on growth, yield, and water use efficiency (WUE) of rice grown under four irrigation deficit treatments (i.e., irrigation every 3, 6, 9 and 12 d). The irrigation every 3 d was considered as the control in the current study. For this purpose, biochar was prepared through the pyrolysis of corn stalk and rice husk at 350 °C for 3 h, while sonochemical combined with the precipitation method was used to prepare zinc oxide nanoparticles (ZnO NPs) from zinc acetate. The morphological structures of the produced biochar and ZnO NPs were characterized using X-ray diffraction (XRD), N₂ gas adsorption-desorption, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results exhibited that the combination of biochar alongside ZnO NPs resulted in a positive significant effect on the physiological traits such as chlorophyll content, relative water content, plant height, and leaf area index as well as yield-associated components (i.e., number of panicles m⁻², number of filled grain per panicle, 1000-grain weight), and biological and grain yield ha⁻¹ when rice plants were irrigated every 9 days without a significant difference with those obtained from the control treatment (irrigation every 3 d). In conclusion, the combination of biochar and ZnO NPs could be recommended as an optimal approach to maximize both grain yield ha⁻¹ and WUE of rice.

The current study was designed to assess the effect of different concentrations of silica oxide nanoparticles (SiO₂NPs) (0, 30, 60, and 90 ppm) as foliar applications under three irrigation regimes i.e., irrigation every 3 days (IR3, control), irrigation every 6 days (IR6), and irrigation every 9 days (IR9) on growth, yield and certain metabolites of rice (Oryza sativa L. cv. EHR1). To achieve such a goal, 2 field experiments were conducted during the 2018 and 2019 seasons at the Experimental Farm of Rice Research and Training Center (RRTC), Sakha Agricultural Station, Kafr El-sheik, Egypt. Firstly, the as-prepared nanoparticles of SiO₂ were prepared from useless materials (RHs) which are considered as one of the bio burdens on the environment via treating with HCl and followed by drying and calcination. Consequently, the synthesis was examined by making use of advanced tools such as X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic light scattering (DLS) for illustrating the hydrodynamic particle size of SiO₂NPs and scanning electron microscopy (SEM). The nanoparticles were formed with nearly spherical shape and small size. The results indicated that leaf area index, dry matter production, the number of panicles/m², the number of filled grains/ panicles, 1000 grain weight, grain yield, and biological yield as well as chlorophyll content have witnessed a significant increase under irrigated application every 3 and 6 days. Whilst a prolonged irrigation regime up to 9 days recorded a remarkable decline in the aforementioned characteristics except for the number of unfilled grains/panicle which increased considerably in both seasons. On the other hand, proline concentration and the activity of the antioxidant enzymes were increased in both irrigated treatments every 6 and 9 days compared with control treatment (irrigation every 3 days). The foliar supplementations of (SiO₂NPs) contributed to ameliorating all the aforementioned characteristics progressively up to the dosage of 90 ppm compared to control treatment (no Si/NPS application) in both seasons. Invariably, growth and yield parameters in water-stressed plants treated with SiO₂NPs were higher than those in water-stressed plants without SiO₂NPs addition. Based on that, it could be concluded that the foliar application of SiO₂NPs can mitigate the adverse effect of water stress on rice plants.

In paddy fields, overuse of nitrogen fertilizer to maximize yields can lead to excessive economic loss and degradation of the environment. Therefore, studying the effects of urea–chitosan nanohybrid as a slow released source of nitrogen fertilizer on rice cultivation was the aim of our study. The effects of fertilization applications, namely: CU: control treatment; U1: application of a full recommended dose of classical urea (165 kg N ha⁻¹); U2: adding recommended dose of classical urea by 80% + exogenous urea–chitosan nanohybrid 250 mg N/L; U3: adding recommended dose of classical urea by 80% + exogenous urea–chitosan nanohybrid 500 mg N/L; U4: adding recommended dose of classical urea by 60% + exogenous urea–chitosan nanohybrid 250 mg N/L; U5: adding recommended dose of classical urea by 60% + exogenous urea–chitosan nanohybrid 500 mg N/L; U6: adding recommended dose of classical urea by 40% + exogenous urea–chitosan nanohybrid 250 mg N/L; and U7: adding recommended dose of classical urea by 40% + exogenous urea–chitosan nanohybrid 500 mg N/L on growth indicators, yield-related components, grain productivity, and N uptake status of rice plants were investigated during two successive seasons. As a result, significant achievements concerning growth, yield and yield-related traits were obtained when rice plants were fertilized with exogenous urea–chitosan nanohybrid (i.e., 500 mg N/L) + 60% classical urea without a significant decline in the studied traits compared to the full recommended dose of classical urea. Accordingly, this investigation revealed that chitosan nanohybrid at 500 mg N/L as a compensatory alternative can be used in saving 40% of classical urea requirement.

The excessive application of synthetic fertilizers can result in severe environmental risks, while composting green and fresh feedstocks can provide slow-release nutrients. Therefore, the aim of the current investigation was to study the effects of eight individual and combination treatments of azolla compost and NPK synthetic fertilizers (control = no fertilizer and compost; 100% NPK = full recommended dose of synthetic fertilizers as follows: 165 kg N ha⁻¹, 37 kg P₂O₅ ha⁻¹ and 50 kg K₂O ha⁻¹; 70% NPK; 40% NPK; 100% azolla compost (5 t DM ha⁻¹); 50% NPK + 50% azolla compost; 70% NPK + 30% azolla compost and 40% NPK + 60% azolla compost) on rice growth, productivity and nutrient uptake in semi-arid agro-ecosystems. The results indicated that the combination of 40% NPK + 60% azolla compost or 50% NPK + 50% azolla compost resulted in the most optimal growth and the highest yield components. In addition, the application of 40% NPK + 60% azolla compost exhibited similar rice grain yields (10.76 t ha⁻¹) as well as N, P, and K content and uptake compared with the full recommended dose of NPK fertilizer (100% NPK). This study declared that the utilization of azolla compost as an individual or combination application can reduce usage of synthetic fertilizers by up to 60% without significant reduction in the growth and grain productivity of rice.

Studies were carried in the two seasons of 2017 and 2018 at the Experimental Farm of El-Sirw Agriculture Research Station, Damietta Governorate, Egypt. The main objective of study was to determine the effect of foliar spraying with some chemical substances during panicle initiation+ mid booting stages on rice growth, yield, yield attributes and grains quality characteristics of rice cv. Giza179. The experimental design was performed in randomized complete block design with four replications. Foliar application treatments were 1-Control (non-treated treatment), 2-Di ammonium phosphate spray (DAP 1.5%) 3- Potassium (K2O 1.5%) 4- N+K+ mixture (1.5% for each) 5- Gibbrilic acid (GA310ppm)+K+ (1.5%) 6- Salicylic acid (SA 500ppm)+K(1.5%) 7- Humic acid (HA)+1.5%K). Salinity levels of experimental were 8.4 and 8.5 dSm-1 in both seasons, respectively. The plant growth, yield, yield components parameters, and grains quality characteristics were collected. The tested chemical substance significantly improved the studied characteristics rice grain quality, yields and yield contributes compared with the control treatment. Foliar spray with mixture of humic acid +K+ at panicle initiation + mid booting stages was significantly the most efficient treatment in improving rice grain quality, growth and yields without significant difference with the mixture of N+K treatment regarding rice grain quality improvement. The mixture of humic+ K+ could be recommended for improving rice quality and productivity of Giza 179 under salt stress.