Neighborhood systems are used to approximate graphs as finite topological structures. Throughout this article, we construct new types of eight neighborhoods for vertices of an arbitrary graph, say, j-adhesion neighborhoods. Both notions of Allam et al. and Yao will be extended via j-adhesion neighborhoods. We investigate new types of j-lower approximations and j-upper approximations for any subgraph of a given graph. Then, the accuracy of these approximations will be calculated. Moreover, a comparison between accuracy measures and boundary regions for different kinds of approximations will be discussed. To generate j-adhesion neighborhoods and rough sets on graphs, some algorithms will be introduced. Finally, a sample of a chemical example for Walczak will be introduced to illustrate our proposed methods.