A fiber-optics tapered sensor that is covered by an electrospinning polyvinyl alcohol (PVA) nanofiber film, is demonstrated to measure humidity and temperature simultaneously. A section multi-mode fiber (MMF) was sandwiched between two leading-in and out single mode fibers (SMFs), which was further tapered down to 29 μm to promote the humidity sensitivity of the sensor. A thin layer of electrospinning PVA nanofiber film was uniformly coated on the MMF taper region by electrospinning technology. In order to promote the humidity sensitivity and mechanical strength of electrospinning nanofibers, the carbon nanotubes (CNTs) were mixed into PVA to formed PVA/CNTs composite nanofiber film. A Fiber Bragg Grating (FBG) was cascaded with the humidity sensing fiber to monitor the ambient temperature simultaneously. The addition of CNTs effectively eliminated the cracks on the electrospinning nanofiber and made it more uniform and smoother. As experimental results show, the humidity sensitivity of the sensor with PVA/CNTs film was 0.0484 dB/%RH, an improvement of 31.16% compared to that of the sensor with PVA film, for which sensitivity is 0.0369 dB/%RH. The nanofiber humidity-sensitive film constructed using electrospinning had a satisfactory humidity response, special 3D structure and extensive application prospect.

The immobilization of enzymes is always an important factor that limits the development of biosensors. Especially for optical fiber biosensors, it is usually necessary to modify the surface of the optical fiber through complex chemical reactions so that enzymes can be attached to the surface firmly. In this article, we used the enzyme immobilization method of electrospinning on the optical fiber sensor for the first time. The detection of glucose was realized by using electrospinning to fix a layer of crosslinked polyvinyl alcohol nanofibers that encapsulated glucose oxidase on the surface of the side-polished D-shape optical fiber. The experimental results show that the sensitivity of the designed sensor is 1.875dB/(mg/ml) when the glucose concentration range is 0mg/ml~4mg/ml. The electrospinning method of optical fiber enzyme immobilization is very promising and can be used to rapidly develop more other types of optical fiber biosensors.

In recent years, owing to the continuous development of polymer nanofiber manufacturing technology, various nanofibers with different structural characteristics have emerged, allowing their application in the field of sensing to continually expand. Integrating polymer nanofibers with optical sensors takes advantage of the high sensitivity, fast response, and strong immunity to electromagnetic interference of optical sensors, enabling widespread use in biomedical science, environmental monitoring, food safety, and other fields. This paper summarizes the research progress of polymer nanofibers in optical sensors, classifies and analyzes polymer nanofiber optical sensors according to different functions (fluorescence, Raman, polarization, surface plasmon resonance, and photoelectrochemistry), and introduces the principles, structures, and properties of each type of sensor and application examples in different fields. This paper also looks forward to the future development directions and challenges of polymer nanofiber optical sensors, and provides a reference for in-depth research of sensors and industrial applications of polymer nanofibers.