Large-scale production of conical carbon nanostructures is possible through pyrolysis of hydrocarbons in a plasma torch process. The resulting carbon cones occur in five distinctly different forms, and disc-shaped particles are produced as well. The structure and properties of these carbon cones and discs have been relatively little explored until now. Here we characterize the structure of these particles using transmission electron microscopy, synchrotron x-ray and electron diffraction. The carbon nanocones are found to exhibit several interesting structural features; instead of having a uniform cross-section, the walls consist of a relatively thin inner graphite-like layer with a non-crystalline envelope, where the amount of the latter can be modified significantly by annealing. The cones appear with a well-defined faceting along the cone edge, demonstrating strict long-range atomic ordering; they also present occasional examples of symmetry breaking, such as two apexes appearing in the same carbon nanocone.

A good material for CO₂ capture should possess some specific properties: (i) a large effective surface area with good adsorption capacity, (ii) selectivity for CO₂, (iii) regeneration capacity with minimum energy input, allowing reutilization of the material for CO₂ adsorption and (iv) low cost and high environmental friendliness. Smectite clays are layered nanoporous materials that may be good candidates in this context. Here we report experiments which show that gaseous CO₂ intercalates into the interlayer nano-space of smectite clay (synthetic fluorohectorite) at conditions close to ambient. The rate of intercalation, as well as the retention ability of CO₂ was found to be strongly dependent on the type of the interlayer cation, which in the present case is Li⁺, Na⁺ or Ni²⁺. Interestingly, we observe that the smectite Li-fluorohectorite is able to retain CO₂ up to a temperature of 35°C at ambient pressure and that the captured CO₂ can be released by heating above this temperature. Our estimates indicate that smectite clays, even with the standard cations analyzed here, can capture an amount of CO₂ comparable to other materials studied in this context.