Laboratoire des Multimatériaux et Interfaces (LMI-UMR 5615 CNRS / UCBL), Domaine Scientifique de la Doua, Université Claude Bernard Lyon 1, Bâtiment Chevreul, 6 rue Victor Grignard, 69622 Villeurbanne Cedex, France
Prof. Catherine Journet
Laboratoire des Multimatériaux et Interfaces (LMI-UMR 5615 CNRS / UCBL), Domaine Scientifique de la Doua, Université Claude Bernard Lyon 1, Bâtiment Chevreul, 6 rue Victor Grignard, 69622 Villeurbanne Cedex, France
A simple method was used to assemble single-walled carbon nanotubes into indefinitely long ribbons and fibers. The processing consists of dispersing the nanotubes in surfactant solutions, recondensing the nanotubes in the flow of a polymer solution to form a nanotube mesh, and then collating this mesh to a nanotube fiber. Flow-induced alignment may lead to a preferential orientation of the nanotubes in the mesh that has the form of a ribbon. Unlike classical carbon fibers, the nanotube fibers can be strongly bent without breaking. Their obtained elastic modulus is 10 times higher than the modulus of high-quality bucky paper.
We present in this Letter an experimental characterization of liquid flow slippage over superhydrophobic surfaces made of carbon nanotube forests, incorporated in microchannels. We make use of a particle image velocimetry technique to achieve the submicrometric resolution on the flow profile necessary for accurate measurement of the surface hydrodynamic properties. We demonstrate boundary slippage on the Cassie superhydrophobic state, associated with slip lengths of a few microns, while a vanishing slip length is found in the Wenzel state when the liquid impregnates the surface. Varying the lateral roughness scale of our carbon nanotube forest-based superhydrophobic surfaces, we demonstrate that the slip length varies linearly with in line with theoretical predictions for slippage on patterned surfaces.
Proximity-induced superconductivity in single-walled carbon nanotubes below 1 kelvin, both in a single tube 1 nanometer in diameter and in crystalline ropes containing about 100 nanotubes, was observed. The samples were suspended between two superconducting electrodes, permitting structural study in a transmission electron microscope. When the resistance of the nanotube junction is sufficiently low, it becomes superconducting and can carry high supercurrents. The temperature and magnetic field dependence of the critical current of such junctions exhibits unusual features related to their strong one-dimensional character.
Field emission (FE) electron spectroscopy from an individual multiwalled carbon nanotube (MWNT) is used to measure quantitatively stable temperatures at the apex, , of up to 2000 K induced by FE currents . The high is due to Joule heating along the length of the MWNT. These measurements also give directly the resistance of the individual MWNT which is shown to decrease with temperature, and explain the phenomenon of FE-induced light emission which was observed simultaneously. The heating permits thermal desorption of the MWNT and, hence, excellent current stability.
The catalytic growth of single-wall carbon nanotubes is investigated by high-resolution transmission electron microscopy. The similarities between the samples synthesized from different techniques suggest a common growth mechanism based on a vapor-liquid-solid model. Quantum-molecular-dynamics simulations support a root growth mechanism where carbon atoms are incorporated into the tube base by a diffusion-segregation process.