It has been shown that the temperature behavior of dielectric permittivity () in the isotropic phase of nematogens can be described in the same way as in critical binary solutions. Hence, using a relation with the critical exponent it was possible to portray the results of measurements in the isotropic phase of 5-heptyl-2-(4′-cyanobiphenyl)-pyrimidine and 4,4--octylcyanobiphenyl. The influence of the position of the permanent dipole moment on the results was tested by additional measurements in -(-methoxybenzylidene)--butylaniline. It also has been shown that a fluidlike analogy can be applied to the nonlinear dielectric effect (NDE), which describes changes of dielectric permittivity induced by a strong electric field. Measurements were conducted for the lowest frequency used in NDE studies ( kHz), so the condition (with the relaxation time) was always fulfilled. Values of discontinuities of the isotropicnematic phase transition from both the analysis of measurements and NDE studies are in good agreement.
Dielectric relaxation and measurements were carried out on propylene carbonate. From these, we show that thermal energy exerts a stronger influence than volume on the temperature dependence of the dynamic properties. Data obtained at all temperatures and pressures superimpose, when expressed as a function of . The scaling exponent is consistent with more thermally governed dynamics, and can be interpreted as a reflection of the soft nature of the potential. The change of dynamics observed in the conductivity and relaxation data transpires at a fixed value of either quantity, independent of temperature and pressure.
We discuss the phenomenology related to the pressure behavior of viscosity in low-molecular-weight glass-forming liquids. We show that the effect of pressure on viscosity in two examined glass-forming systems, salol and ortho-terphenyl, can be satisfactorily described, over considerable ranges of pressure (up to 1 GPa) and temperature (300–425 K), by the two-parameter pressure law which has been proposed previously for the relaxation time shift. The presented analysis indicates that one of the parameters (the pressure counterpart of the Vogel-Fulcher-Tammann law parameter D, which accounts for the fragility of a glass former) is independent of temperature in salol and ortho-terphenyl. As a consequence, the scaling plot which normalizes data collected for different temperatures can be constructed for a given glass former. On the basis of the presented considerations, a general form of the temperature-pressure viscosity “equation of state” is proposed.